A Novel Tetrameric Heptomolybdate with Reactive Oxygen Species Catalytic Ability
A novel polymolybdate based on tetrameric {Mo 7 O 24 } cluster and copper complexes [Na(H 2 O) 7 ] 6 [Cu(En) 2 ] 4 {[Na(H 2 O)][H 1.5 Mo 7 O 24 ]} 4 ·3H 2 O ( I , En = ethylenediamine) has been designed and characterized by IR spectrum, UV spectrum and single-crystal X-ray diffraction (CIF file CCDC...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2022-05, Vol.48 (5), p.325-331 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A novel polymolybdate based on tetrameric {Mo
7
O
24
} cluster and copper complexes [Na(H
2
O)
7
]
6
[Cu(En)
2
]
4
{[Na(H
2
O)][H
1.5
Mo
7
O
24
]}
4
·3H
2
O (
I
, En = ethylenediamine) has been designed and characterized by IR spectrum, UV spectrum and single-crystal X-ray diffraction (CIF file CCDC no. 2104092). Structural data show that the main structure of
I
is a circular polyoxoanion that is alternately joined by [Mo
7
O
24
]
6–
clusters and sodium ions. The cations of
I
are in forms: [Cu(En)
2
]
2+
and [Na(H
2
O)
7
]
+
. Notably,
I
can efficiently catalyze the production of reactive oxygen species. |
|---|---|
| ISSN: | 1070-3284 1608-3318 |
| DOI: | 10.1134/S1070328422050050 |