Structural and Optical Properties of Two-Step Dip-Coated CH3NH3PbI3 Films Based on Underlying Dip-Coated PbI2 Films
Thin films of methylammonium lead iodide (MAPbI 3 ) were deposited on glass slides under various preparation conditions by a two-step dip-coating method, using dip-coated lead iodide (PbI 2 ) thin films as the underlying layer. The dip-coating method used involved immersion of a slowly rotating subs...
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Veröffentlicht in: | Journal of electronic materials 2022-07, Vol.51 (7), p.3873-3884 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Thin films of methylammonium lead iodide (MAPbI
3
) were deposited on glass slides under various preparation conditions by a two-step dip-coating method, using dip-coated lead iodide (PbI
2
) thin films as the underlying layer. The dip-coating method used involved immersion of a slowly rotating substrate in the required solution. The PbI
2
film was immersed into methylammonium iodide (MAI) solution in 2-propanol for 10–60 min. The MAPbI
3
films were thermally annealed at 85 °C for 10–30 min. Fundamental properties of the annealed MAPbI
3
films were studied by x-ray diffraction (XRD), scanning electron microscopy (SEM) and ultraviolet-visible spectrophotometry. The XRD patterns and SEM micrographs revealed single tetragonal-phase structure, with diffraction peaks became intense and narrow with increasing dipping times and upon thermal annealing. Transmittance spectra of these MAPbI
3
film/glass systems declined steeply near
780
nm
, equivalent to a bandgap energy of
1.55
eV
, assigned to the MAPbI
3
with optical absorption coefficient of
10
5
cm
-
1
. |
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ISSN: | 0361-5235 1543-186X |
DOI: | 10.1007/s11664-022-09637-0 |