NMR Characterization of the Higher Molecular Weight Byproducts Formed During the Synthesis of [PCl2N]3
The by-product chlorophosphazenes obtained from the reaction of PCl5 and NH4Cl at ∼ 140°, have been characterized by 2D 31P–15N HMQC and DOSY NMR spectroscopy. These NMR spectra show that the byproducts are a very complex mixture.
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Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2007-06, Vol.17 (2), p.477-481 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | The by-product chlorophosphazenes obtained from the reaction of PCl5 and NH4Cl at ∼ 140°, have been characterized by 2D 31P–15N HMQC and DOSY NMR spectroscopy. These NMR spectra show that the byproducts are a very complex mixture. |
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ISSN: | 1574-1443 1574-1451 |
DOI: | 10.1007/s10904-007-9135-2 |