Pd‐Catalyzed Decarboxylative Coupling Between Allyl Carbonates and Vinyl Benzoxazinanones

Pd‐Catalyzed Decarboxylative Coupling Between Allyl Carbonates and Vinyl Benzoxazinanones

In the presence of Pd(OAc)2/biphenyl‐based phosphoramidite ligand(±)‐L4,the decarboxylative coupling of allyl carbonates with vinyl benzoxazinanonesoccurred readily, and deliveredthe desired productsin the acceptable chemical yields. The chemical structure of the obtained compounds was clearly ident...

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Veröffentlicht in:Advanced synthesis & catalysis 2022-05, Vol.364 (10), p.1738-1749
Hauptverfasser: Cai, Lu‐Yu, Zhang, Heng, Wang, Kuo, Zhao, Hong‐Wu
Format: Artikel
Sprache:eng
Schlagworte:
allyl carbonate
Carbonates
Coupling
Crystals
decarboxylative coupling
Palladium
Pd-catalysis
Single crystals
vinyl benzoxazinone
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Zusammenfassung:In the presence of Pd(OAc)2/biphenyl‐based phosphoramidite ligand(±)‐L4,the decarboxylative coupling of allyl carbonates with vinyl benzoxazinanonesoccurred readily, and deliveredthe desired productsin the acceptable chemical yields. The chemical structure of the obtained compounds was clearly identified by a single crystal X‐ray analysis.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.202200125