Oxygen incorporation in AllnP, and its effect on P-type doping with magnesium

Oxygen incorporation in AlyIn1−yP (y ∼ 0.5) grown by metalorganic chemical vapor deposition (MOCVD) has been studied as a function of PH3 flow, growth temperature, and alloy composition. Both O2 and diethylaluminum ethoxide (DEAlO) were employed as sources of oxygen. The incorporation of oxygen was...

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Veröffentlicht in:Journal of electronic materials 1999-07, Vol.28 (7), p.916-925
Hauptverfasser: Stockman, S. A., Huang, J. -W., Osentowski, T. D., Chui, H. C., Peanasky, M. J., Maranowski, S. A., Grillot, P. N., Moll, A. J., Chen, C. H., Kuo, C. P., Liang, B. W.
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container_end_page 925
container_issue 7
container_start_page 916
container_title Journal of electronic materials
container_volume 28
creator Stockman, S. A.
Huang, J. -W.
Osentowski, T. D.
Chui, H. C.
Peanasky, M. J.
Maranowski, S. A.
Grillot, P. N.
Moll, A. J.
Chen, C. H.
Kuo, C. P.
Liang, B. W.
description Oxygen incorporation in AlyIn1−yP (y ∼ 0.5) grown by metalorganic chemical vapor deposition (MOCVD) has been studied as a function of PH3 flow, growth temperature, and alloy composition. Both O2 and diethylaluminum ethoxide (DEAlO) were employed as sources of oxygen. The incorporation of oxygen was found to be a superlinear function of O2 or DEAlO flow. When multiple sources of oxygen are present, a surface interaction leads to enhanced oxygen incorporation. Oxygen incorporation cannot be adequately described by a simple dependence on growth temperature or V/III ratio due to strong interactions between these variables. In Mg-doped AlInP co-doped with oxygen, the incorporation of both Mg and O is strongly affected by an interaction between the two species, and roughly 10% of the oxygen atoms act as compensating donors.
doi_str_mv 10.1007/s11664-999-0220-x
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A. ; Huang, J. -W. ; Osentowski, T. D. ; Chui, H. C. ; Peanasky, M. J. ; Maranowski, S. A. ; Grillot, P. N. ; Moll, A. J. ; Chen, C. H. ; Kuo, C. P. ; Liang, B. W.</creator><creatorcontrib>Stockman, S. A. ; Huang, J. -W. ; Osentowski, T. D. ; Chui, H. C. ; Peanasky, M. J. ; Maranowski, S. A. ; Grillot, P. N. ; Moll, A. J. ; Chen, C. H. ; Kuo, C. P. ; Liang, B. W.</creatorcontrib><description>Oxygen incorporation in AlyIn1−yP (y ∼ 0.5) grown by metalorganic chemical vapor deposition (MOCVD) has been studied as a function of PH3 flow, growth temperature, and alloy composition. Both O2 and diethylaluminum ethoxide (DEAlO) were employed as sources of oxygen. The incorporation of oxygen was found to be a superlinear function of O2 or DEAlO flow. When multiple sources of oxygen are present, a surface interaction leads to enhanced oxygen incorporation. 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subjects Incorporation
Magnesium
Metalorganic chemical vapor deposition
Oxygen atoms
Temperature dependence
title Oxygen incorporation in AllnP, and its effect on P-type doping with magnesium
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