Synthesis and crystal structure of Isotrithionedithiolato-bis(phenanthroline)zinc(II)

Synthesis and crystal structure of Isotrithionedithiolato-bis(phenanthroline)zinc(II)

The synthesis of a mixed-ligand complex 1,3-dithiole-2-thione-4,5-dithiolato-bis(1,10-phenanthroline)zinc(II), [Zn(Dmit)(Phen)2], is described. The crystals are monoclinic, space group P21/n, a = 11.868(2) Å, b = 13.122(3) Å, c = 17.010(3) Å, β = 102.01(3)°, Z = 4. The coordination polyhedron of the...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Russian journal of coordination chemistry 2006-04, Vol.32 (4), p.237-241
Hauptverfasser: Vitushkina, S. V., Starodub, V. A., Pyshkin, O. S.
Format: Artikel
Sprache:eng
Schlagworte:
Coordination compounds
Crystal structure
Crystals
Infrared spectroscopy
Ligands
Nitrogen atoms
Synthesis
Zinc
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The synthesis of a mixed-ligand complex 1,3-dithiole-2-thione-4,5-dithiolato-bis(1,10-phenanthroline)zinc(II), [Zn(Dmit)(Phen)2], is described. The crystals are monoclinic, space group P21/n, a = 11.868(2) Å, b = 13.122(3) Å, c = 17.010(3) Å, β = 102.01(3)°, Z = 4. The coordination polyhedron of the Zn(II) atom is an octahedron formed by two sulfur atoms of the Dmit ligand and four nitrogen atoms of the two Phen ligands. The complex is studied by IR and UV spectroscopy.
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328406040026