Enthalpies molaires de melange a T=303,15 K des systemes binaires liquides de cyclohexanone avec chloroethanes

Experimental heats of mixing ΔmixH at 303.15 K and normal atmospheric pressure were obtained for the binary mixtures cyclohexanone+(1,2-dichloroethane, 1,1,1-trichloroethane, 1,1,2-trichloroethane,1,1,2,2-tetrachloroethane or pentachloroethane), using a Calvet microcalorimeter. The ΔmixH values for...

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Veröffentlicht in:Journal of thermal analysis and calorimetry 2002-01, Vol.68 (3), p.887-892
Hauptverfasser: Tafat-Igoudjilene, O, Ait, Kaci A, Rogalski, M
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Sprache:eng
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Zusammenfassung:Experimental heats of mixing ΔmixH at 303.15 K and normal atmospheric pressure were obtained for the binary mixtures cyclohexanone+(1,2-dichloroethane, 1,1,1-trichloroethane, 1,1,2-trichloroethane,1,1,2,2-tetrachloroethane or pentachloroethane), using a Calvet microcalorimeter. The ΔmixH values for all the mixtures were negative, indicated that important interaction occur between the ketoxy group and chloroalcane.
ISSN:1388-6150
1588-2926
DOI:10.1023/A:1016182220638