Cyclopropenes and methylenecyclopropanes in 1,3-dipolar cycloaddition reactions

Cyclopropenes and methylenecyclopropanes in 1,3-dipolar cycloaddition reactions

The review considers the main results of the cycloaddition reactions involving cyclopropenes and methylenecyclopropanes, the compounds bearing strained three-membered rings and, respectively, endo- and exocyclic double bonds. The main attention is focused on the reactions of these compounds with 1,3...

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Veröffentlicht in:Russian chemical bulletin 2022, Vol.71 (4), p.620-650
Hauptverfasser: Molchanov, A. P., Efremova, M. M., Kuznetsov, M. A.
Format: Artikel
Sprache:eng
Schlagworte:
Carbonyls
Chemical bonds
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Cycloaddition
Dipoles
Imines
Inorganic Chemistry
Organic Chemistry
Organic compounds
Review
Stereoselectivity
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Beschreibung
Zusammenfassung:The review considers the main results of the cycloaddition reactions involving cyclopropenes and methylenecyclopropanes, the compounds bearing strained three-membered rings and, respectively, endo- and exocyclic double bonds. The main attention is focused on the reactions of these compounds with 1,3-dipoles (nitrones, azomethine imines, azomethine ylides, carbonyl ylides, etc. ), which gave complex heterocyclic systems with high regio- and stereoselectivity.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-022-3460-z