The As2Te3–Сr2Тe3 System
Chemical reactions between As 2 Te 3 and Сr 2 Тe 3 in the As 2 Te 3 –Сr 2 Тe 3 system, which is a quasi-binary section of the As–Cr–Te ternary system, were studied by physicochemical methods (DTA, XRD, microstructure observations, microhardness measurements, and density determinations), and a releva...
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| Veröffentlicht in: | Russian journal of inorganic chemistry 2022-04, Vol.67 (4), p.492-496 |
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| container_title | Russian journal of inorganic chemistry |
| container_volume | 67 |
| creator | Aliev, I. I. Ismailova, S. Sh Babanly, K. N. Mekhtieva, S. T. |
| description | Chemical reactions between As
2
Te
3
and Сr
2
Тe
3
in the As
2
Te
3
–Сr
2
Тe
3
system, which is a quasi-binary section of the As–Cr–Te ternary system, were studied by physicochemical methods (DTA, XRD, microstructure observations, microhardness measurements, and density determinations), and a relevant
Т–х
diagram was plotted. The As
2
Te
3
–Cr
2
Te
3
system forms one chemical compound, namely, CrAsTe
3
, which melts incongruently at 375°C. Microstructural analysis showed that at room temperature, As
2
Te
3
-base solid solutions extend to 3.5 mol % Cr
2
Te
3
and Cr
2
Te
3
-base solid solutions extend to 5 mol % As
2
Te
3
. The α phase (As
2
Te
3
-base solid solutions) and CrAsТe
3
form a 15 mol % Cr
2
Тe
3
eutectic at 335°С. X-ray diffraction showed that CrAsТe
3
crystallizes in tetragonal crystal system with the unit cell parameters
a
= 14.246 Å,
c
= 5.993 Å, ρ
pycn
= 6.57 g/cm
3
, ρ
x
= 6.96 g/cm
3
. |
| doi_str_mv | 10.1134/S0036023622040039 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2652090627</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2652090627</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2319-e48e595b975e6b3ba534da5d7930005603b3ef6127411e3747664c29f226d77f3</originalsourceid><addsrcrecordid>eNp1kE1KA0EQhRtRcIweQHARcD1aXdU_08sQ_IOAi4zrZn5q1GB-7E4W2XkHT6Anyhk8iTOM4EJc1YP3vlfwhDiVcCElqcspABlAMoigWu32RCI1yTQzkvZF0tlp5x-KoxhnAEqBzRJxlj_xcBQxZ_p6e999BNx9Mg2n27jm-bE4aIqXyCc_dyAerq_y8W06ub-5G48maYUkXcoqY-106axmU1JZaFJ1oWvrCAC0ASqJGyPRKimZrLLGqApdg2hqaxsaiPO-dxWWrxuOaz9bbsKifenRaAQHBm2bkn2qCssYAzd-FZ7nRdh6Cb4bwf8ZoWWwZ2KbXTxy-G3-H_oGTTpbFg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2652090627</pqid></control><display><type>article</type><title>The As2Te3–Сr2Тe3 System</title><source>SpringerLink Journals - AutoHoldings</source><creator>Aliev, I. I. ; Ismailova, S. Sh ; Babanly, K. N. ; Mekhtieva, S. T.</creator><creatorcontrib>Aliev, I. I. ; Ismailova, S. Sh ; Babanly, K. N. ; Mekhtieva, S. T.</creatorcontrib><description>Chemical reactions between As
2
Te
3
and Сr
2
Тe
3
in the As
2
Te
3
–Сr
2
Тe
3
system, which is a quasi-binary section of the As–Cr–Te ternary system, were studied by physicochemical methods (DTA, XRD, microstructure observations, microhardness measurements, and density determinations), and a relevant
Т–х
diagram was plotted. The As
2
Te
3
–Cr
2
Te
3
system forms one chemical compound, namely, CrAsTe
3
, which melts incongruently at 375°C. Microstructural analysis showed that at room temperature, As
2
Te
3
-base solid solutions extend to 3.5 mol % Cr
2
Te
3
and Cr
2
Te
3
-base solid solutions extend to 5 mol % As
2
Te
3
. The α phase (As
2
Te
3
-base solid solutions) and CrAsТe
3
form a 15 mol % Cr
2
Тe
3
eutectic at 335°С. X-ray diffraction showed that CrAsТe
3
crystallizes in tetragonal crystal system with the unit cell parameters
a
= 14.246 Å,
c
= 5.993 Å, ρ
pycn
= 6.57 g/cm
3
, ρ
x
= 6.96 g/cm
3
.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023622040039</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemical compounds ; Chemical reactions ; Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Microhardness ; Microstructural analysis ; Microstructure ; Physicochemical Analysis of Inorganic Systems ; Room temperature ; Solid solutions ; Ternary systems ; Unit cell</subject><ispartof>Russian journal of inorganic chemistry, 2022-04, Vol.67 (4), p.492-496</ispartof><rights>Pleiades Publishing, Ltd. 2022. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2022, Vol. 67, No. 4, pp. 492–496. © Pleiades Publishing, Ltd., 2022. Russian Text © The Author(s), 2022, published in Zhurnal Neorganicheskoi Khimii, 2022, Vol. 67, No. 4, pp. 497–501.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2319-e48e595b975e6b3ba534da5d7930005603b3ef6127411e3747664c29f226d77f3</citedby><cites>FETCH-LOGICAL-c2319-e48e595b975e6b3ba534da5d7930005603b3ef6127411e3747664c29f226d77f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036023622040039$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036023622040039$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Aliev, I. I.</creatorcontrib><creatorcontrib>Ismailova, S. Sh</creatorcontrib><creatorcontrib>Babanly, K. N.</creatorcontrib><creatorcontrib>Mekhtieva, S. T.</creatorcontrib><title>The As2Te3–Сr2Тe3 System</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>Chemical reactions between As
2
Te
3
and Сr
2
Тe
3
in the As
2
Te
3
–Сr
2
Тe
3
system, which is a quasi-binary section of the As–Cr–Te ternary system, were studied by physicochemical methods (DTA, XRD, microstructure observations, microhardness measurements, and density determinations), and a relevant
Т–х
diagram was plotted. The As
2
Te
3
–Cr
2
Te
3
system forms one chemical compound, namely, CrAsTe
3
, which melts incongruently at 375°C. Microstructural analysis showed that at room temperature, As
2
Te
3
-base solid solutions extend to 3.5 mol % Cr
2
Te
3
and Cr
2
Te
3
-base solid solutions extend to 5 mol % As
2
Te
3
. The α phase (As
2
Te
3
-base solid solutions) and CrAsТe
3
form a 15 mol % Cr
2
Тe
3
eutectic at 335°С. X-ray diffraction showed that CrAsТe
3
crystallizes in tetragonal crystal system with the unit cell parameters
a
= 14.246 Å,
c
= 5.993 Å, ρ
pycn
= 6.57 g/cm
3
, ρ
x
= 6.96 g/cm
3
.</description><subject>Chemical compounds</subject><subject>Chemical reactions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Microhardness</subject><subject>Microstructural analysis</subject><subject>Microstructure</subject><subject>Physicochemical Analysis of Inorganic Systems</subject><subject>Room temperature</subject><subject>Solid solutions</subject><subject>Ternary systems</subject><subject>Unit cell</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kE1KA0EQhRtRcIweQHARcD1aXdU_08sQ_IOAi4zrZn5q1GB-7E4W2XkHT6Anyhk8iTOM4EJc1YP3vlfwhDiVcCElqcspABlAMoigWu32RCI1yTQzkvZF0tlp5x-KoxhnAEqBzRJxlj_xcBQxZ_p6e999BNx9Mg2n27jm-bE4aIqXyCc_dyAerq_y8W06ub-5G48maYUkXcoqY-106axmU1JZaFJ1oWvrCAC0ASqJGyPRKimZrLLGqApdg2hqaxsaiPO-dxWWrxuOaz9bbsKifenRaAQHBm2bkn2qCssYAzd-FZ7nRdh6Cb4bwf8ZoWWwZ2KbXTxy-G3-H_oGTTpbFg</recordid><startdate>20220401</startdate><enddate>20220401</enddate><creator>Aliev, I. I.</creator><creator>Ismailova, S. Sh</creator><creator>Babanly, K. N.</creator><creator>Mekhtieva, S. T.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20220401</creationdate><title>The As2Te3–Сr2Тe3 System</title><author>Aliev, I. I. ; Ismailova, S. Sh ; Babanly, K. N. ; Mekhtieva, S. T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2319-e48e595b975e6b3ba534da5d7930005603b3ef6127411e3747664c29f226d77f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Chemical compounds</topic><topic>Chemical reactions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Microhardness</topic><topic>Microstructural analysis</topic><topic>Microstructure</topic><topic>Physicochemical Analysis of Inorganic Systems</topic><topic>Room temperature</topic><topic>Solid solutions</topic><topic>Ternary systems</topic><topic>Unit cell</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aliev, I. I.</creatorcontrib><creatorcontrib>Ismailova, S. Sh</creatorcontrib><creatorcontrib>Babanly, K. N.</creatorcontrib><creatorcontrib>Mekhtieva, S. T.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aliev, I. I.</au><au>Ismailova, S. Sh</au><au>Babanly, K. N.</au><au>Mekhtieva, S. T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The As2Te3–Сr2Тe3 System</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2022-04-01</date><risdate>2022</risdate><volume>67</volume><issue>4</issue><spage>492</spage><epage>496</epage><pages>492-496</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>Chemical reactions between As
2
Te
3
and Сr
2
Тe
3
in the As
2
Te
3
–Сr
2
Тe
3
system, which is a quasi-binary section of the As–Cr–Te ternary system, were studied by physicochemical methods (DTA, XRD, microstructure observations, microhardness measurements, and density determinations), and a relevant
Т–х
diagram was plotted. The As
2
Te
3
–Cr
2
Te
3
system forms one chemical compound, namely, CrAsTe
3
, which melts incongruently at 375°C. Microstructural analysis showed that at room temperature, As
2
Te
3
-base solid solutions extend to 3.5 mol % Cr
2
Te
3
and Cr
2
Te
3
-base solid solutions extend to 5 mol % As
2
Te
3
. The α phase (As
2
Te
3
-base solid solutions) and CrAsТe
3
form a 15 mol % Cr
2
Тe
3
eutectic at 335°С. X-ray diffraction showed that CrAsТe
3
crystallizes in tetragonal crystal system with the unit cell parameters
a
= 14.246 Å,
c
= 5.993 Å, ρ
pycn
= 6.57 g/cm
3
, ρ
x
= 6.96 g/cm
3
.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023622040039</doi><tpages>5</tpages></addata></record> |
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| issn | 0036-0236 1531-8613 |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Chemical compounds Chemical reactions Chemistry Chemistry and Materials Science Inorganic Chemistry Microhardness Microstructural analysis Microstructure Physicochemical Analysis of Inorganic Systems Room temperature Solid solutions Ternary systems Unit cell |
| title | The As2Te3–Сr2Тe3 System |
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