Thermal Decomposition of Co–Cu Double Salicylate Complex under Argon Atmosphere Resulting in Metal–Carbon Compositions

Thermal Decomposition of Co–Cu Double Salicylate Complex under Argon Atmosphere Resulting in Metal–Carbon Compositions

Thermal decomposition of double complex (DC) [Co(NH 3 ) 6 ]Cl[Cu(C 7 H 4 O 3 ) 2 ] · 3H 2 O under inert atmosphere (argon) at high (>700°C) temperatures leads to formation of metal–carbon Co–Cu–C compositions. The reaction proceeds by sequential elimination of coordinated ammonia from the cationi...

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Veröffentlicht in:Russian journal of inorganic chemistry 2022-04, Vol.67 (4), p.555-559
Hauptverfasser: Domonov, D. P., Pechenyuk, S. I., Semushina, Yu. P.
Format: Artikel
Sprache:eng
Schlagworte:
Ammonia
Argon
Chemistry
Chemistry and Materials Science
Composition
Copper
Decomposition
Inert atmospheres
Inorganic Chemistry
Inorganic Materials and Nanomaterials
Thermal decomposition
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Zusammenfassung:Thermal decomposition of double complex (DC) [Co(NH 3 ) 6 ]Cl[Cu(C 7 H 4 O 3 ) 2 ] · 3H 2 O under inert atmosphere (argon) at high (>700°C) temperatures leads to formation of metal–carbon Co–Cu–C compositions. The reaction proceeds by sequential elimination of coordinated ammonia from the cationic portion of DC and decomposition of coordinated salicylate with evolution of phenol and its derivatives.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023622040040