SnO2-Fe2O3 embedded in graphene nanosheets enhances conductivity and stable structure as a high-performance anode material for lithium-ion batteries
SnO 2 /Fe 2 O 3 /graphene nanocomposites were prepared by ball milling in planetary ball mill. SnO 2 /Fe 2 O 3 nanoparticles are homogeneously fixed in graphite dilute nanosheets. It is worth noting that Fe 2 O 3 nanoparticles can inhibit the agglomeration of SnO 2 and it can also shorten the propag...
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Veröffentlicht in: | Ionics 2022, Vol.28 (5), p.2213-2226 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | SnO
2
/Fe
2
O
3
/graphene nanocomposites were prepared by ball milling in planetary ball mill. SnO
2
/Fe
2
O
3
nanoparticles are homogeneously fixed in graphite dilute nanosheets. It is worth noting that Fe
2
O
3
nanoparticles can inhibit the agglomeration of SnO
2
and it can also shorten the propagation path of Li
+
and electrons. The nanostructure of graphene has excellent electrical conductivity and mechanical properties, which can simultaneously buffer the SnO
2
volume change, inhibit the pulverization of the Fe
2
O
3
, and enhance the electrical contact of the electrode. Consequently, SnO
2
/Fe
2
O
3
/graphene nanocomposite material after 100 cycles displayed an excellent reversible capacity of 1280.2 mA/g at 0.2 A/g, with an outstanding rate capacity of 669.5 mA/g even at 1.0 A/g. After 450 cycles, the nanocomposite material achieved outstanding long-term cycling stability of 1694.9 mAg
−1
at 1.0 Ag
−1
. |
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ISSN: | 0947-7047 1862-0760 |
DOI: | 10.1007/s11581-021-04401-6 |