Zirconium-Gallic Acid Coordination Polymer: Catalytic Transfer Hydrogenation of Levulinic Acid and Its Esters into γ-Valerolactone
The conversion of ethyl levulinate (EL) to produce γ-valerolactone (GVL) through catalytic transfer hydrogenation (CTH) reaction plays a crucial role in the field of biomass catalytic conversion. In this work, a novel Zr-base catalyst with phenate group, phenolic hydroxyl and carboxyl in its structu...
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Veröffentlicht in: | Catalysis letters 2022-05, Vol.152 (5), p.1286-1297 |
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Sprache: | eng |
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Zusammenfassung: | The conversion of ethyl levulinate (EL) to produce γ-valerolactone (GVL) through catalytic transfer hydrogenation (CTH) reaction plays a crucial role in the field of biomass catalytic conversion. In this work, a novel Zr-base catalyst with phenate group, phenolic hydroxyl and carboxyl in its structure was prepared by the co-precipitation of natural sources gallic acid and ZrCl
4
. It was found that Zr-GA has an excellent catalytic performance for this reaction and satisfactory GVL yield could be achieved. Besides, Zr-GA could be easily separated from the reaction system and reused at least six times without a significantly decrease in activity. Meanwhile, various characterizations had proved that Zr-GA is a porous material with acid–base bifunctional sites. The main reason for the high catalytic activity of the Zr-GA was that the synergetic effects of Lewis acid/base sites and Brønsted acid sites and appropriate textural properties. In addition, a possible reaction mechanism was proposed in conjunction with the poisoning experiment and previous reports. The heterogeneous catalyst Zr-GA prepared with gallic acid as a raw material has low cost and recyclability, and has great potential in green chemistry.
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ISSN: | 1011-372X 1572-879X |
DOI: | 10.1007/s10562-021-03724-3 |