Mix and wait - a relaxed way for synthesizing ZIF-8

Mix and wait - a relaxed way for synthesizing ZIF-8

Herein we report the synthesis of a zeolitic imidazolate framework (ZIF-8) by an easy "mix and wait" procedure. In a closed vial, without any interference, the mixture of 2-methylimidazole and basic zinc carbonate assembles into the crystalline product with approx. 90% conversion after 70...

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Veröffentlicht in:RSC advances 2022-03, Vol.12 (15), p.894-8944
Hauptverfasser: Gugin, Nikita, Villajos, Jose A, Feldmann, Ines, Emmerling, Franziska
Format: Artikel
Sprache:eng
Schlagworte:
Basic converters
Chemistry
Metal-organic frameworks
Zeolites
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Zusammenfassung:Herein we report the synthesis of a zeolitic imidazolate framework (ZIF-8) by an easy "mix and wait" procedure. In a closed vial, without any interference, the mixture of 2-methylimidazole and basic zinc carbonate assembles into the crystalline product with approx. 90% conversion after 70 h. The reaction exhibits sigmoidal kinetics due to the self-generated water which accelerates the reaction. Herein we report the synthesis of a zeolitic imidazolate framework (ZIF-8) by an easy "mix and wait" procedure.
ISSN:2046-2069
2046-2069
DOI:10.1039/d2ra00740a