Impact of the Manufacturing Processes of Aromatic-Polymer-Based Carbon Fiber on Life Cycle Greenhouse Gas Emissions
Carbon fibers (CFs) are promising lightweight materials to reduce vehicle fuel consumption. However, the most widely used polyacrylonitrile (PAN)-based CF production process consumes a considerable amount of energy. A novel production process for CFs from aromatic polymers (APs) is proposed as an al...
Gespeichert in:
Veröffentlicht in: | Sustainability 2022-03, Vol.14 (6), p.3541 |
---|---|
Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | Carbon fibers (CFs) are promising lightweight materials to reduce vehicle fuel consumption. However, the most widely used polyacrylonitrile (PAN)-based CF production process consumes a considerable amount of energy. A novel production process for CFs from aromatic polymers (APs) is proposed as an alternative. In this study, the greenhouse gas (GHG) emissions from PAN-based CFs, from APs using the classical benzidine method, and from APs using the coupling method on a cradle-to-gate basis, were analyzed. The results indicate that the AP CFs with the classical benzidine method generated 11% fewer GHG emissions compared with the conventional PAN CFs. Emissions were further reduced by 42% using a large-tow production process. As the classical benzidine method for manufacturing CFs from APs uses a monomer synthesized via benzidine, which is carcinogenic, we examined a different synthetic route using the coupling method for monomer synthesis to avoid the benzidine intermediate. The GHG emissions from the AP CFs manufactured by the coupling method showed a 51% increase compared with PAN-based CFs, indicating a trade-off between GHG emissions and carcinogenicity. However, with proper chemical management, the classical method of CF manufacturing from APs via benzidine showed reduced GHG emissions. |
---|---|
ISSN: | 2071-1050 2071-1050 |
DOI: | 10.3390/su14063541 |