A supramolecular glass made from a low molecular weight amino acid derivative

[Display omitted] •A nitro-aromatic urea derivative of tyrosine assembles into a novel bio-derived glass.•The molecular transparent glass can be reprocessed via either solution or melt casting.•Supramolecular assembly was assessed via variable-temperature infrared spectroscopy. A low molecular weigh...

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Veröffentlicht in:European polymer journal 2022-01, Vol.162, p.110889, Article 110889
Hauptverfasser: Baker, B.C., O'Donnell, A.D., Priya, Hyder, M., German, I.M., Hayes, W.
Format: Artikel
Sprache:eng
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Zusammenfassung:[Display omitted] •A nitro-aromatic urea derivative of tyrosine assembles into a novel bio-derived glass.•The molecular transparent glass can be reprocessed via either solution or melt casting.•Supramolecular assembly was assessed via variable-temperature infrared spectroscopy. A low molecular weight tyrosine derivative with self-assembling capabilities has been found to form a robust optically transparent supramolecular glass after casting at 70 °C. The glass films are remarkably stable, remaining transparent over 12 + months as well as in contact with water and can be reprocessed via solvation in a wide range of organic solvents. The solubility, long-term stability and thermo-responsive properties of the bio-derived glass makes it an ideal candidate for use as a window where its reprocessability at easily accessible temperatures are attractive.
ISSN:0014-3057
1873-1945
DOI:10.1016/j.eurpolymj.2021.110889