A supramolecular glass made from a low molecular weight amino acid derivative
[Display omitted] •A nitro-aromatic urea derivative of tyrosine assembles into a novel bio-derived glass.•The molecular transparent glass can be reprocessed via either solution or melt casting.•Supramolecular assembly was assessed via variable-temperature infrared spectroscopy. A low molecular weigh...
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Veröffentlicht in: | European polymer journal 2022-01, Vol.162, p.110889, Article 110889 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | [Display omitted]
•A nitro-aromatic urea derivative of tyrosine assembles into a novel bio-derived glass.•The molecular transparent glass can be reprocessed via either solution or melt casting.•Supramolecular assembly was assessed via variable-temperature infrared spectroscopy.
A low molecular weight tyrosine derivative with self-assembling capabilities has been found to form a robust optically transparent supramolecular glass after casting at 70 °C. The glass films are remarkably stable, remaining transparent over 12 + months as well as in contact with water and can be reprocessed via solvation in a wide range of organic solvents. The solubility, long-term stability and thermo-responsive properties of the bio-derived glass makes it an ideal candidate for use as a window where its reprocessability at easily accessible temperatures are attractive. |
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ISSN: | 0014-3057 1873-1945 |
DOI: | 10.1016/j.eurpolymj.2021.110889 |