Preparation of porous TiNi-Ti alloy by diffusion sintering method and study of its composition, structure and martensitic transformations

•Sintering of TiNi and Ti powders controls phase composition of formed porous alloy and atomic composition of its matrix.•Addition of 5-10 at.% of Ti leads to the Ti:Ni ratio close to 1:1.•At 5 at% of Ti additive the alloy contains a minimum concentration of secondary precipitates and Ti:Ni ratio close to 1:1.•Austenite-to-martensite transformation in all the samples proceeds in two stages through the R-phase.•Addition of 5 at% of Ti results in TiNi-Ti alloy with martensite transformation temperatures attractive for implants. [Display omitted] The study demonstrates a method for controlling not only the phase composition but also the atomic composition of TiNi matrix in porous TiNi-Ti alloys developed for biomedical uses as implants. The alloys were obtained from TiNi powder which was sintered with Ti powder added at as much as 0–10 at%. The structure, phase and chemical composition of the produced TiNi-Ti alloys was investigated with respect to the amount of Ti added into the material. It is shown that in the sintered product containing 5 at% and more of Ti additive, the composition of its TiNi matrix becomes close to equiatomic (with Ti:Ni atomic ratio ~1), and the excessive Ti precipitates as secondary phases Ti2Ni and Ti3Ni4. In parallel, with increase in Ti additive from 0–10 at%, the structure of the precipitating Ti2Ni type phases changes its morphology from separate spherical or pyramidal precipitates to large dendritic formations. The direct martensitic transformation from austenite to martensite in all the samples was found to proceed in two stages and through the R-phase (B2→R→B19′). Thermoresistive analysis demonstrated that TiNi-Ti samples with 5 and more at% of Ti had their characteristic starting temperature of martensite transition stabilizing at ~57 °C (330 K). This implies that the sample with 5 at% of Ti additive exhibited desired martensite transition temperatures, while containing a minimum concentration of secondary-phase precipitates in its matrix which deteriorate its properties. Thus, for the first time, we show that a very simple preparation approach based on sintering powders of TiNi and Ti is capable of producing porous TiNi-Ti alloys with properties optimized for fabricating bone implants.