Rhodium-catalyzed dearomative rearrangement of 2-oxypyridines with cyclopropenes: access to N -alkylated 2-pyridones
A rhodium-catalyzed dearomative rearrangement reaction of 2-oxypyridines has been developed by using cyclopropenes as carbene precursors. This protocol features broad substrate scope and mild reaction conditions, providing a reliable and practical approach for the highly efficient synthesis of 2-alk...
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| Veröffentlicht in: | Organic Chemistry Frontiers 2022-03, Vol.9 (5), p.1295-1299 |
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| container_title | Organic Chemistry Frontiers |
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| creator | Cui, Honglian Xu, Guangyang Zhu, Jie Sun, Jiangtao |
| description | A rhodium-catalyzed dearomative rearrangement reaction of 2-oxypyridines has been developed by using cyclopropenes as carbene precursors. This protocol features broad substrate scope and mild reaction conditions, providing a reliable and practical approach for the highly efficient synthesis of 2-alkylated 2-pyridone derivatives from readily available
O
-substituted pyridine compounds. |
| doi_str_mv | 10.1039/D1QO01937F |
| format | Article |
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O
-substituted pyridine compounds.</description><identifier>ISSN: 2052-4129</identifier><identifier>ISSN: 2052-4110</identifier><identifier>EISSN: 2052-4129</identifier><identifier>EISSN: 2052-4110</identifier><identifier>DOI: 10.1039/D1QO01937F</identifier><language>eng</language><publisher>London: Royal Society of Chemistry</publisher><subject>Alkylation ; Catalysis ; Organic chemistry ; Organic compounds ; Rhodium ; Substrates</subject><ispartof>Organic Chemistry Frontiers, 2022-03, Vol.9 (5), p.1295-1299</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c259t-8e7a22cdcfe8b41b6370419addd9eb88d943720097babdc99defee86a1ccbe8e3</citedby><cites>FETCH-LOGICAL-c259t-8e7a22cdcfe8b41b6370419addd9eb88d943720097babdc99defee86a1ccbe8e3</cites><orcidid>0000-0003-2516-3466</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27907,27908</link.rule.ids></links><search><creatorcontrib>Cui, Honglian</creatorcontrib><creatorcontrib>Xu, Guangyang</creatorcontrib><creatorcontrib>Zhu, Jie</creatorcontrib><creatorcontrib>Sun, Jiangtao</creatorcontrib><title>Rhodium-catalyzed dearomative rearrangement of 2-oxypyridines with cyclopropenes: access to N -alkylated 2-pyridones</title><title>Organic Chemistry Frontiers</title><description>A rhodium-catalyzed dearomative rearrangement reaction of 2-oxypyridines has been developed by using cyclopropenes as carbene precursors. This protocol features broad substrate scope and mild reaction conditions, providing a reliable and practical approach for the highly efficient synthesis of 2-alkylated 2-pyridone derivatives from readily available
O
-substituted pyridine compounds.</description><subject>Alkylation</subject><subject>Catalysis</subject><subject>Organic chemistry</subject><subject>Organic compounds</subject><subject>Rhodium</subject><subject>Substrates</subject><issn>2052-4129</issn><issn>2052-4110</issn><issn>2052-4129</issn><issn>2052-4110</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpNkFtLxDAQhYMouOi--AsCvgnRXHqLb7K6Kiwuij6XNJm6XdumJlm1_nqjK-jTHIZvzhwOQkeMnjIq5Nklu19SJkU-30ETTlNOEsbl7j-9j6berymljKcZTfMJCg8ra5pNR7QKqh0_wWADytlOheYNsIvaqf4ZOugDtjXmxH6Mw-ga0_Tg8XsTVliPurWDswPE1TlWWoP3OFh8h4lqX8ZWhWjLyc-Zjcwh2qtV62H6Ow_Q0_zqcXZDFsvr29nFgmieykAKyBXn2ugaiiphVSZymjCpjDESqqIwMhE5p1TmlaqMltJADVBkimldQQHiAB1vfWO41w34UK7txvXxZckzkWQiTRIWqZMtpZ313kFdDq7plBtLRsvvYsu_YsUXki9ttA</recordid><startdate>20220301</startdate><enddate>20220301</enddate><creator>Cui, Honglian</creator><creator>Xu, Guangyang</creator><creator>Zhu, Jie</creator><creator>Sun, Jiangtao</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>P64</scope><orcidid>https://orcid.org/0000-0003-2516-3466</orcidid></search><sort><creationdate>20220301</creationdate><title>Rhodium-catalyzed dearomative rearrangement of 2-oxypyridines with cyclopropenes: access to N -alkylated 2-pyridones</title><author>Cui, Honglian ; Xu, Guangyang ; Zhu, Jie ; Sun, Jiangtao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c259t-8e7a22cdcfe8b41b6370419addd9eb88d943720097babdc99defee86a1ccbe8e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Alkylation</topic><topic>Catalysis</topic><topic>Organic chemistry</topic><topic>Organic compounds</topic><topic>Rhodium</topic><topic>Substrates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cui, Honglian</creatorcontrib><creatorcontrib>Xu, Guangyang</creatorcontrib><creatorcontrib>Zhu, Jie</creatorcontrib><creatorcontrib>Sun, Jiangtao</creatorcontrib><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Organic Chemistry Frontiers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cui, Honglian</au><au>Xu, Guangyang</au><au>Zhu, Jie</au><au>Sun, Jiangtao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rhodium-catalyzed dearomative rearrangement of 2-oxypyridines with cyclopropenes: access to N -alkylated 2-pyridones</atitle><jtitle>Organic Chemistry Frontiers</jtitle><date>2022-03-01</date><risdate>2022</risdate><volume>9</volume><issue>5</issue><spage>1295</spage><epage>1299</epage><pages>1295-1299</pages><issn>2052-4129</issn><issn>2052-4110</issn><eissn>2052-4129</eissn><eissn>2052-4110</eissn><abstract>A rhodium-catalyzed dearomative rearrangement reaction of 2-oxypyridines has been developed by using cyclopropenes as carbene precursors. This protocol features broad substrate scope and mild reaction conditions, providing a reliable and practical approach for the highly efficient synthesis of 2-alkylated 2-pyridone derivatives from readily available
O
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| identifier | ISSN: 2052-4129 |
| ispartof | Organic Chemistry Frontiers, 2022-03, Vol.9 (5), p.1295-1299 |
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| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Alkylation Catalysis Organic chemistry Organic compounds Rhodium Substrates |
| title | Rhodium-catalyzed dearomative rearrangement of 2-oxypyridines with cyclopropenes: access to N -alkylated 2-pyridones |
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