A Safer Alternative for the Mercury Beating Heart Demonstration

The mercury beating heart is a classic demonstration to introduce redox reactions in the classroom. Here we report a new, safer demonstration: the Galinstan beating heart. Galinstan is a commercially available eutectic alloy composed of gallium (68.5%), indium (21.5%), and tin (10%) that has low tox...

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Veröffentlicht in:Journal of chemical education 2022-02, Vol.99 (2), p.1095-1099
Hauptverfasser: Wang, Bingxing, Jiang, Xiaoying, Zhang, Yu, Yu, Lu, Zhang, Yuping
Format: Artikel
Sprache:eng
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Zusammenfassung:The mercury beating heart is a classic demonstration to introduce redox reactions in the classroom. Here we report a new, safer demonstration: the Galinstan beating heart. Galinstan is a commercially available eutectic alloy composed of gallium (68.5%), indium (21.5%), and tin (10%) that has low toxicity. When an iron nail touches the Galinstan drop in a sulfuric acid solution, a steady beating heart behavior is observed. The mechanism of the Galinstan beating heart was attributed to electron transfer from the Galinstan drop to the iron nail, which induces a charge redistribution and an interfacial tension gradient on the drop.
ISSN:0021-9584
1938-1328
DOI:10.1021/acs.jchemed.1c00933