SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF ZINC AND CADMIUM COORDINATION POLYMERS CONSTRUCTED BY 2-PHENYLBUTANEDIOIC ACID AND BIS(4-(1H-IMIDAZOL-1-YL)PHENYL) METHANONE LIGANDS

SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF ZINC AND CADMIUM COORDINATION POLYMERS CONSTRUCTED BY 2-PHENYLBUTANEDIOIC ACID AND BIS(4-(1H-IMIDAZOL-1-YL)PHENYL) METHANONE LIGANDS

Two coordination polymers [(L 1 )Zn(pbtda)] n ( 1 ) and [(L 1 )Cd(H 2 O)(pbtda)] n ( 2 ), (L 1  = bis(4-(1 H -imidazol-1-yl)phenyl)methanone, H 2 pbtda = 2-phenylbutanedioic acid) are prepared under solvothermal conditions. They are characterized by elemental analyses, IR spectroscopy, and X-ray cry...

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Veröffentlicht in:Journal of structural chemistry 2021-01, Vol.62 (Suppl 1), p.S1-S7
Hauptverfasser: Wang, G.-F., Sun, S.-W.
Format: Artikel
Sprache:eng
Schlagworte:
Atomic
Atomic/Molecular Structure and Spectra
Chemistry
Chemistry and Materials Science
Coordination polymers
Crystallography
Infrared spectroscopy
Inorganic Chemistry
Molecular
Optical and Plasma Physics
Physical Chemistry
Solid State Physics
Structural analysis
Topology
Zinc
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Zusammenfassung:Two coordination polymers [(L 1 )Zn(pbtda)] n ( 1 ) and [(L 1 )Cd(H 2 O)(pbtda)] n ( 2 ), (L 1  = bis(4-(1 H -imidazol-1-yl)phenyl)methanone, H 2 pbtda = 2-phenylbutanedioic acid) are prepared under solvothermal conditions. They are characterized by elemental analyses, IR spectroscopy, and X-ray crystallography. Complex 2 forms a 1D chain, while complex 1 has a 2D structure of the {4 4 ·6 2 } topology along the [1 0 –2] direction.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476621130011