Structural, thermal, and mechanical properties of gelatin-based films integrated with tara gum

Films with different morphology can be obtained by mixing fish gelatin, Tara gum and glycerol in different ratio and by subjecting the Tara gum to a ball milling treatment before its use. The amount of the plasticizer glycerol, as well as the type of Tara gum employed (as received or milled) resulte...

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Veröffentlicht in:Polymer (Guilford) 2021-02, Vol.214, p.123244, Article 123244
Hauptverfasser: Nuvoli, Luca, Conte, Paola, Fadda, Costantino, Reglero Ruiz, José Antonio, García, José M., Baldino, Salvatore, Mannu, Alberto
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Sprache:eng
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Zusammenfassung:Films with different morphology can be obtained by mixing fish gelatin, Tara gum and glycerol in different ratio and by subjecting the Tara gum to a ball milling treatment before its use. The amount of the plasticizer glycerol, as well as the type of Tara gum employed (as received or milled) resulted, from SEM and AFM analyses, to strong influencing the morphology of the films and their density. Also, the morphological differences determine different thermal and mechanical behaviours. In particular, the employment of milled Tara gum allows to improve the thermal stability, as well as the mechanical properties of the polymers. A similar outcome can be obtained by increasing the glycerol content, which can be used up to 20 wt%. Glycerol amounts exceeding that percentage, are detrimental for the quality of the films and reduce their thermal and mechanical performances. [Display omitted] •Novel films based on fish gelatin and tara gum were obtained.•Films were fabricated following a simple casting process.•Density of films varied between 6.5 and 9.8 g/cm3, using glycerol as plasticizer.•High degradation temperatures (up to 300 °C) were observed.•Milling Tara gum improved both thermal stability and mechanical strength.
ISSN:0032-3861
1873-2291
DOI:10.1016/j.polymer.2020.123244