Neutron diffraction evidence of the 3-dimensional structure of Ba2MnTeO6 and misidentification of the triangular layers within the face-centred cubic lattice

Ba2MnTeO6 was first characterised using X-ray diffraction and reported to show a small distortion1 from the idealised cubic perovskite which displays face-centred cubic arrangement of Mn2+. A recent report has asserted that this leads to a layered configuration of Mn2+ that serves as an example of a...

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Veröffentlicht in:arXiv.org 2022-02
Hauptverfasser: Mustonen, Otto H J, Pughe, Charlotte E, Walker, Helen C, Mutch, Heather M, Stenning, Gavin B G, Coomer, Fiona C, Cussen, Edmund J
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Sprache:eng
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Zusammenfassung:Ba2MnTeO6 was first characterised using X-ray diffraction and reported to show a small distortion1 from the idealised cubic perovskite which displays face-centred cubic arrangement of Mn2+. A recent report has asserted that this leads to a layered configuration of Mn2+ that serves as an example of a triangular lattice, i.e. a 2D structure containing discreet layers.2 Here we show how neutron scattering gives great confidence in establishing the crystal structure being an undistorted cubic phase and how this can be mis-assigned as a triangular layered structure. This has profound implications for the understanding of the magnetic properties of the system.
ISSN:2331-8422