Flexible N-doped TiO2/C nanofibrous film-based photocatalytic fabric with high photocatalytic activity and excellent reusability
The flexible nitrogen (N) doped TiO 2 /C nanofibrous film (NTC f ) was fabricated by a combination of electrospinning and annealing treatment. The BET surface area of the NTC f increases, reaches largest value, and then decreases slightly with increasing of N. And the NTC f -20 has a maximum BET sur...
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Veröffentlicht in: | Applied physics. A, Materials science & processing Materials science & processing, 2022-02, Vol.128 (2), Article 138 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The flexible nitrogen (N) doped TiO
2
/C nanofibrous film (NTC
f
) was fabricated by a combination of electrospinning and annealing treatment. The BET surface area of the NTC
f
increases, reaches largest value, and then decreases slightly with increasing of N. And the NTC
f
-20 has a maximum BET surface area of 175.60 m
2
·g
−1
. These are beneficial to the absorption of dye by the photocatalyst. At the same time, the N doping could increase the light absorption of TiO
2
and is favorable to the charges transfer of the carbon nanofibers, resulting in improving the photocatalytic activity of NTC
f
under visible light. As a result, all the NTC
f
showed excellent photocatalytic performance. Moreover, with the increase of N concentration, the photocatalytic activity of the NTC
f
increased, reaching the largest value before decreasing. And the highest photocatalytic degradation efficiency of Rhodamine B (RhB) was about 99.1% for 1 h by using NTC
f
-20. After that, the NTC
f
film was stuck on organza fabric to form a photocatalytic fabric by hot pressing. And the photocatalytic fabric with degradation efficiency of 98.5% was easily separated from the dye solution and possessed excellent reusability. It has huge potential application in pollutant disposal in flowing water. |
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ISSN: | 0947-8396 1432-0630 |
DOI: | 10.1007/s00339-021-05184-3 |