Preparing water-based phosphorylated PEEK sizing agent for CF/PEEK interface enhancement
The weak interfacial bonding between fiber and matrix needs to be improved for obtaining good mechanical properties of carbon fiber/polyetheretherketone (CF/PEEK) composites due to the inert nature of both components. Organic sizing is a typical interface improvement method, but it is harmful to bot...
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Veröffentlicht in: | Composites science and technology 2022-01, Vol.217, p.109096, Article 109096 |
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creator | Lyu, Hanxiong Jiang, Naiyu Hu, Jiqiang Li, Yingze Zhou, Nan Zhang, Dongxing |
description | The weak interfacial bonding between fiber and matrix needs to be improved for obtaining good mechanical properties of carbon fiber/polyetheretherketone (CF/PEEK) composites due to the inert nature of both components. Organic sizing is a typical interface improvement method, but it is harmful to both the human and local environment. Here, a two-step process is proposed to modify PEEK for preparing an environmentally friendly water-based sizing agent, involving taking the ketone reduction via NaBH4 and then an esterification reaction with phosphoric acid. This PEEK derivative has good thermal stability, and its dispersion in water is stable for one month. It improves the interface between CF and PEEK by increasing the wettability and surface roughness of CFs, ultimately enhancing the mechanical properties of composites. The two-step process of fabricating the PEEK derivative may have potentials in the industrial application of the polyaryletherketone family.
[Display omitted]
•Proposing a novel and facile two-step modification route on PEEK.•Preparing eco-friendly water-based phosphorylated PEEK sizing agent.•Excellent dispersion stability of phosphorylated PEEK in water over one month.•Enhancing interface between CF and PEEK by phosphorylated PEEK sizing. |
doi_str_mv | 10.1016/j.compscitech.2021.109096 |
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[Display omitted]
•Proposing a novel and facile two-step modification route on PEEK.•Preparing eco-friendly water-based phosphorylated PEEK sizing agent.•Excellent dispersion stability of phosphorylated PEEK in water over one month.•Enhancing interface between CF and PEEK by phosphorylated PEEK sizing.</description><identifier>ISSN: 0266-3538</identifier><identifier>EISSN: 1879-1050</identifier><identifier>DOI: 10.1016/j.compscitech.2021.109096</identifier><language>eng</language><publisher>Barking: Elsevier Ltd</publisher><subject>Bonding agents ; Bonding strength ; Carbon fiber reinforced plastics ; Carbon fibers ; Composite materials ; Esterification ; Industrial applications ; Interface ; Mechanical properties ; Nanoparticles ; Phosphoric acid ; Polyaryletherketones ; Polyether ether ketones ; Polymer matrix composites ; Polymer-matrix composites (PMCs) ; Sizing ; Surface roughness ; Surface treatments ; Thermal stability ; Wettability</subject><ispartof>Composites science and technology, 2022-01, Vol.217, p.109096, Article 109096</ispartof><rights>2021 Elsevier Ltd</rights><rights>Copyright Elsevier BV Jan 5, 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c349t-d82f96aacbc3d7417fffc7c030c58a242cb5e7094c4852b7aad4f19328b455373</citedby><cites>FETCH-LOGICAL-c349t-d82f96aacbc3d7417fffc7c030c58a242cb5e7094c4852b7aad4f19328b455373</cites><orcidid>0000-0001-5661-7200 ; 0000-0002-7446-2297</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0266353821004528$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65534</link.rule.ids></links><search><creatorcontrib>Lyu, Hanxiong</creatorcontrib><creatorcontrib>Jiang, Naiyu</creatorcontrib><creatorcontrib>Hu, Jiqiang</creatorcontrib><creatorcontrib>Li, Yingze</creatorcontrib><creatorcontrib>Zhou, Nan</creatorcontrib><creatorcontrib>Zhang, Dongxing</creatorcontrib><title>Preparing water-based phosphorylated PEEK sizing agent for CF/PEEK interface enhancement</title><title>Composites science and technology</title><description>The weak interfacial bonding between fiber and matrix needs to be improved for obtaining good mechanical properties of carbon fiber/polyetheretherketone (CF/PEEK) composites due to the inert nature of both components. Organic sizing is a typical interface improvement method, but it is harmful to both the human and local environment. Here, a two-step process is proposed to modify PEEK for preparing an environmentally friendly water-based sizing agent, involving taking the ketone reduction via NaBH4 and then an esterification reaction with phosphoric acid. This PEEK derivative has good thermal stability, and its dispersion in water is stable for one month. It improves the interface between CF and PEEK by increasing the wettability and surface roughness of CFs, ultimately enhancing the mechanical properties of composites. The two-step process of fabricating the PEEK derivative may have potentials in the industrial application of the polyaryletherketone family.
[Display omitted]
•Proposing a novel and facile two-step modification route on PEEK.•Preparing eco-friendly water-based phosphorylated PEEK sizing agent.•Excellent dispersion stability of phosphorylated PEEK in water over one month.•Enhancing interface between CF and PEEK by phosphorylated PEEK sizing.</description><subject>Bonding agents</subject><subject>Bonding strength</subject><subject>Carbon fiber reinforced plastics</subject><subject>Carbon fibers</subject><subject>Composite materials</subject><subject>Esterification</subject><subject>Industrial applications</subject><subject>Interface</subject><subject>Mechanical properties</subject><subject>Nanoparticles</subject><subject>Phosphoric acid</subject><subject>Polyaryletherketones</subject><subject>Polyether ether ketones</subject><subject>Polymer matrix composites</subject><subject>Polymer-matrix composites (PMCs)</subject><subject>Sizing</subject><subject>Surface roughness</subject><subject>Surface treatments</subject><subject>Thermal stability</subject><subject>Wettability</subject><issn>0266-3538</issn><issn>1879-1050</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNqNkMtOwzAQRS0EEuXxD0Gs0_oRx_ESRS0gKtEFSOwsxxm3jtok2CmofD0uYcGSxWikmXNndC9CNwRPCSb5rJmabtcH4wYwmynFlMS5xDI_QRNSCJkSzPEpmmCa5ynjrDhHFyE0GGPBJZ2gt5WHXnvXrpNPPYBPKx2gTvpNF2L5wzYO62Q1nz8lwX0dMb2Gdkhs55NyMftZuDYKrTaQQLvRrYFdJK7QmdXbANe__RK9LuYv5UO6fL5_LO-WqWGZHNK6oFbmWpvKsFpkRFhrjTCYYcMLTTNqKg4Cy8xkBaeV0LrOLJGMFlXGORPsEt2Od3vfve8hDKrp9r6NLxXNiSSkiM4jJUfK-C4ED1b13u20PyiC1TFI1ag_QapjkGoMMmrLUQvRxocDryIF0WbtPJhB1Z37x5VvsuKCJQ</recordid><startdate>20220105</startdate><enddate>20220105</enddate><creator>Lyu, Hanxiong</creator><creator>Jiang, Naiyu</creator><creator>Hu, Jiqiang</creator><creator>Li, Yingze</creator><creator>Zhou, Nan</creator><creator>Zhang, Dongxing</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-5661-7200</orcidid><orcidid>https://orcid.org/0000-0002-7446-2297</orcidid></search><sort><creationdate>20220105</creationdate><title>Preparing water-based phosphorylated PEEK sizing agent for CF/PEEK interface enhancement</title><author>Lyu, Hanxiong ; Jiang, Naiyu ; Hu, Jiqiang ; Li, Yingze ; Zhou, Nan ; Zhang, Dongxing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c349t-d82f96aacbc3d7417fffc7c030c58a242cb5e7094c4852b7aad4f19328b455373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Bonding agents</topic><topic>Bonding strength</topic><topic>Carbon fiber reinforced plastics</topic><topic>Carbon fibers</topic><topic>Composite materials</topic><topic>Esterification</topic><topic>Industrial applications</topic><topic>Interface</topic><topic>Mechanical properties</topic><topic>Nanoparticles</topic><topic>Phosphoric acid</topic><topic>Polyaryletherketones</topic><topic>Polyether ether ketones</topic><topic>Polymer matrix composites</topic><topic>Polymer-matrix composites (PMCs)</topic><topic>Sizing</topic><topic>Surface roughness</topic><topic>Surface treatments</topic><topic>Thermal stability</topic><topic>Wettability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lyu, Hanxiong</creatorcontrib><creatorcontrib>Jiang, Naiyu</creatorcontrib><creatorcontrib>Hu, Jiqiang</creatorcontrib><creatorcontrib>Li, Yingze</creatorcontrib><creatorcontrib>Zhou, Nan</creatorcontrib><creatorcontrib>Zhang, Dongxing</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Composites science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lyu, Hanxiong</au><au>Jiang, Naiyu</au><au>Hu, Jiqiang</au><au>Li, Yingze</au><au>Zhou, Nan</au><au>Zhang, Dongxing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparing water-based phosphorylated PEEK sizing agent for CF/PEEK interface enhancement</atitle><jtitle>Composites science and technology</jtitle><date>2022-01-05</date><risdate>2022</risdate><volume>217</volume><spage>109096</spage><pages>109096-</pages><artnum>109096</artnum><issn>0266-3538</issn><eissn>1879-1050</eissn><abstract>The weak interfacial bonding between fiber and matrix needs to be improved for obtaining good mechanical properties of carbon fiber/polyetheretherketone (CF/PEEK) composites due to the inert nature of both components. Organic sizing is a typical interface improvement method, but it is harmful to both the human and local environment. Here, a two-step process is proposed to modify PEEK for preparing an environmentally friendly water-based sizing agent, involving taking the ketone reduction via NaBH4 and then an esterification reaction with phosphoric acid. This PEEK derivative has good thermal stability, and its dispersion in water is stable for one month. It improves the interface between CF and PEEK by increasing the wettability and surface roughness of CFs, ultimately enhancing the mechanical properties of composites. The two-step process of fabricating the PEEK derivative may have potentials in the industrial application of the polyaryletherketone family.
[Display omitted]
•Proposing a novel and facile two-step modification route on PEEK.•Preparing eco-friendly water-based phosphorylated PEEK sizing agent.•Excellent dispersion stability of phosphorylated PEEK in water over one month.•Enhancing interface between CF and PEEK by phosphorylated PEEK sizing.</abstract><cop>Barking</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.compscitech.2021.109096</doi><orcidid>https://orcid.org/0000-0001-5661-7200</orcidid><orcidid>https://orcid.org/0000-0002-7446-2297</orcidid></addata></record> |
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subjects | Bonding agents Bonding strength Carbon fiber reinforced plastics Carbon fibers Composite materials Esterification Industrial applications Interface Mechanical properties Nanoparticles Phosphoric acid Polyaryletherketones Polyether ether ketones Polymer matrix composites Polymer-matrix composites (PMCs) Sizing Surface roughness Surface treatments Thermal stability Wettability |
title | Preparing water-based phosphorylated PEEK sizing agent for CF/PEEK interface enhancement |
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