Extraction-Pyrolysis Synthesis and Luminescence Properties of Lanthanum–Cerium Phosphates Activated by Terbium
A method for producing lanthanum–cerium phosphates activated by terbium of the compositions La 0.8 Ce 0.15 Tb 0.05 PO 4 and La 0.8 Ce 0.15 Tb 0.05 (PO 3 ) 3 has been suggested. The main advantage of this method in comparison with those that are already known is a decrease in temperature and process...
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Veröffentlicht in: | Theoretical foundations of chemical engineering 2021-09, Vol.55 (5), p.1086-1090 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | A method for producing lanthanum–cerium phosphates activated by terbium of the compositions La
0.8
Ce
0.15
Tb
0.05
PO
4
and La
0.8
Ce
0.15
Tb
0.05
(PO
3
)
3
has been suggested. The main advantage of this method in comparison with those that are already known is a decrease in temperature and process time. Luminophores demonstrated an intensive green luminescence in the range 450–620 nm. It has been determined that the intensity of luminescence of the Tb
3+
ion in the presence of La
3+
and Ce
3+
ions increases significantly in comparison with simple terbium phosphates in the compounds, which indicates an increase in the transfer of the excitation energy to the Tb
3+
ion in the presence of activators. |
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ISSN: | 0040-5795 1608-3431 |
DOI: | 10.1134/S0040579520050231 |