Extraction-Pyrolysis Synthesis and Luminescence Properties of Lanthanum–Cerium Phosphates Activated by Terbium

A method for producing lanthanum–cerium phosphates activated by terbium of the compositions La 0.8 Ce 0.15 Tb 0.05 PO 4 and La 0.8 Ce 0.15 Tb 0.05 (PO 3 ) 3 has been suggested. The main advantage of this method in comparison with those that are already known is a decrease in temperature and process...

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Veröffentlicht in:Theoretical foundations of chemical engineering 2021-09, Vol.55 (5), p.1086-1090
Hauptverfasser: Steblevskaya, N. I., Medkov, M. A., Belobeletskaya, M. V.
Format: Artikel
Sprache:eng
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Zusammenfassung:A method for producing lanthanum–cerium phosphates activated by terbium of the compositions La 0.8 Ce 0.15 Tb 0.05 PO 4 and La 0.8 Ce 0.15 Tb 0.05 (PO 3 ) 3 has been suggested. The main advantage of this method in comparison with those that are already known is a decrease in temperature and process time. Luminophores demonstrated an intensive green luminescence in the range 450–620 nm. It has been determined that the intensity of luminescence of the Tb 3+ ion in the presence of La 3+ and Ce 3+ ions increases significantly in comparison with simple terbium phosphates in the compounds, which indicates an increase in the transfer of the excitation energy to the Tb 3+ ion in the presence of activators.
ISSN:0040-5795
1608-3431
DOI:10.1134/S0040579520050231