N-Nitrosation of Glycolurils Catalyzed by 1-Hydroxyethylidene-1,1-diphosphonic Acid

N-Nitrosation of Glycolurils Catalyzed by 1-Hydroxyethylidene-1,1-diphosphonic Acid

A number of N -nitroso derivatives of glycolurils were obtained for the first time, using sodium nitrite and 1-hydroxyethylidene-1,1-diphosphonic acid (HEDP) as a green catalyst. The procedure was carried out in an aqueous heterophase medium without the use of aggressive acids.

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Veröffentlicht in:Russian journal of organic chemistry 2021-11, Vol.57 (11), p.1847-1852
Hauptverfasser: Panshina, S. Yu, Bakibaev, A. A., Borodaenko, A. A., Malkov, V. S.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Organic Chemistry
Sodium nitrite
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Zusammenfassung:A number of N -nitroso derivatives of glycolurils were obtained for the first time, using sodium nitrite and 1-hydroxyethylidene-1,1-diphosphonic acid (HEDP) as a green catalyst. The procedure was carried out in an aqueous heterophase medium without the use of aggressive acids.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428021110063