A NOVEL MERCURY COORDINATION COMPOUND WITH YELLOW PHOTOLUMINESCENCE

The solvothermal reaction of 4,4′-bipyridine (Bipy) and mercury nitrate in a mixed acetonitrile/water solution leads to a novel mercury coordination compound with the in situ formation of cyanide ions Hg(Bipy)(CN) 2 ( 1 ). Its structure is determined by single crystal X-ray diffraction (XRD), and fu...

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Veröffentlicht in:	Journal of structural chemistry 2021-11, Vol.62 (11), p.1810-1817
Hauptverfasser:	Tao, Y. -L., Zhu, Z. -H., Zhao, Z., Zhu, Q. -T., Wang, O., Liu, X.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Atomic Atomic/Molecular Structure and Spectra Chemical analysis Chemistry Chemistry and Materials Science Coordination compounds Crystal structure Infrared analysis Infrared spectroscopy Inorganic Chemistry Mercury compounds Molecular Optical and Plasma Physics Photoluminescence Physical Chemistry Single crystals Solid State Physics X-ray diffraction
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Beschreibung
Zusammenfassung:	The solvothermal reaction of 4,4′-bipyridine (Bipy) and mercury nitrate in a mixed acetonitrile/water solution leads to a novel mercury coordination compound with the in situ formation of cyanide ions Hg(Bipy)(CN) 2 ( 1 ). Its structure is determined by single crystal X-ray diffraction (XRD), and further characterized by powder XRD, elemental analysis, and IR spectroscopy. Compound 1 exhibits a 1D zigzag [Hg(Bipy)(CN) 2 ] n chain structure. The solid-state photoluminescent properties of 1 are also investigated.
ISSN:	0022-4766 1573-8779
DOI:	10.1134/S0022476621110184