The relationship between basic group resonance and quantum yield of high efficiency red light fluorescent solutions
Compared with rare earth elements and heavy metal elements, rare-earth-element-free fluorescent films can greatly reduce environmental hazards. In this study, we use a solution method to produce the fluorescent films. The film thickness is 10 μm, which can maintain fluorescent light intensity in an...
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Veröffentlicht in: | RSC advances 2021-12, Vol.11 (62), p.39142-39146 |
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creator | Lin, Yi-Shan Tsai, Han-Yu Huang, Jung-Kuan Lin, Ching-Fuh |
description | Compared with rare earth elements and heavy metal elements, rare-earth-element-free fluorescent films can greatly reduce environmental hazards. In this study, we use a solution method to produce the fluorescent films. The film thickness is 10 μm, which can maintain fluorescent light intensity in an environment with an average humidity of 55.1 (RH%) after encapsulation. We also find that the type of solvent affects the resonance position of the C&z.tbd;N functional group in DCJTB at a wavenumber of 2196 (cm
−1
), measured with Fourier transform infrared spectroscopy. The functional group is affected by the polar effect with its displacement decreasing with the quantum yield. Finally, we successfully made a fluorescent solution with a resonance displacement of only 12.8 (cm
−1
) for the C&z.tbd;N functional group with the quantum yield being as high as 81.3% and a fluorescent film with a quantum yield as high as 84.8%.
The fluorescent solution with a resonance displacement of only 12.8 (cm
−1
) for the C&z.tbd;N functional group gives this film a quantum yield as high as 84.8%. |
doi_str_mv | 10.1039/d1ra06326j |
format | Article |
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−1
), measured with Fourier transform infrared spectroscopy. The functional group is affected by the polar effect with its displacement decreasing with the quantum yield. Finally, we successfully made a fluorescent solution with a resonance displacement of only 12.8 (cm
−1
) for the C&z.tbd;N functional group with the quantum yield being as high as 81.3% and a fluorescent film with a quantum yield as high as 84.8%.
The fluorescent solution with a resonance displacement of only 12.8 (cm
−1
) for the C&z.tbd;N functional group gives this film a quantum yield as high as 84.8%.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d1ra06326j</identifier><identifier>PMID: 35492482</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Chemistry ; Film thickness ; Fluorescence ; Fourier transforms ; Functional groups ; Heavy metals ; Luminous intensity ; Rare earth elements ; Resonance ; Wavelengths</subject><ispartof>RSC advances, 2021-12, Vol.11 (62), p.39142-39146</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2021</rights><rights>This journal is © The Royal Society of Chemistry 2021 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c428t-91a9d7d135892de1eaa0fbe1054e9a5333992b51cb6a6486a7e428f7ca6271193</citedby><cites>FETCH-LOGICAL-c428t-91a9d7d135892de1eaa0fbe1054e9a5333992b51cb6a6486a7e428f7ca6271193</cites><orcidid>0000-0003-3787-2163</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044458/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044458/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35492482$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Lin, Yi-Shan</creatorcontrib><creatorcontrib>Tsai, Han-Yu</creatorcontrib><creatorcontrib>Huang, Jung-Kuan</creatorcontrib><creatorcontrib>Lin, Ching-Fuh</creatorcontrib><title>The relationship between basic group resonance and quantum yield of high efficiency red light fluorescent solutions</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>Compared with rare earth elements and heavy metal elements, rare-earth-element-free fluorescent films can greatly reduce environmental hazards. In this study, we use a solution method to produce the fluorescent films. The film thickness is 10 μm, which can maintain fluorescent light intensity in an environment with an average humidity of 55.1 (RH%) after encapsulation. We also find that the type of solvent affects the resonance position of the C&z.tbd;N functional group in DCJTB at a wavenumber of 2196 (cm
−1
), measured with Fourier transform infrared spectroscopy. The functional group is affected by the polar effect with its displacement decreasing with the quantum yield. Finally, we successfully made a fluorescent solution with a resonance displacement of only 12.8 (cm
−1
) for the C&z.tbd;N functional group with the quantum yield being as high as 81.3% and a fluorescent film with a quantum yield as high as 84.8%.
The fluorescent solution with a resonance displacement of only 12.8 (cm
−1
) for the C&z.tbd;N functional group gives this film a quantum yield as high as 84.8%.</description><subject>Chemistry</subject><subject>Film thickness</subject><subject>Fluorescence</subject><subject>Fourier transforms</subject><subject>Functional groups</subject><subject>Heavy metals</subject><subject>Luminous intensity</subject><subject>Rare earth elements</subject><subject>Resonance</subject><subject>Wavelengths</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpdkt1rHCEUxaU0NCHNS99bhL6UwjZ-jTO-FEL6kYRAoKTP4jh3dlxc3eiYsv99TTbdpvVF8f7u8VyOCL2h5BMlXJ0ONBkiOZOrF-iIESEXjEj18tn5EJ3kvCJ1yYYySV-hQ94IxUTHjlC-nQAn8GZ2MeTJbXAP8y-AgHuTncXLFMumAjkGEyxgEwZ8V0yYyxpvHfgBxxFPbjlhGEdnHQS7rfiAfb2b8ehLrM0Wwoxz9OXxldfoYDQ-w8nTfox-fvt6e36xuL75fnl-dr2wgnXzQlGjhnagvOkUG4CCMWTsgZJGgDIN51wp1jfU9tJI0UnTQu0bW2skaylV_Bh93uluSr-G4cFEMl5vklubtNXROP1vJbhJL-O9VkQI0XRV4MOTQIp3BfKs167O4r0JEEvWTDadFKJlrKLv_0NXsaRQx6sUUS0jXNJKfdxRNsWcE4x7M5Tohzj1F_rj7DHOqwq_e25_j_4JrwJvd0DKdl_9-x_4byubpn8</recordid><startdate>20211208</startdate><enddate>20211208</enddate><creator>Lin, Yi-Shan</creator><creator>Tsai, Han-Yu</creator><creator>Huang, Jung-Kuan</creator><creator>Lin, Ching-Fuh</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0003-3787-2163</orcidid></search><sort><creationdate>20211208</creationdate><title>The relationship between basic group resonance and quantum yield of high efficiency red light fluorescent solutions</title><author>Lin, Yi-Shan ; Tsai, Han-Yu ; Huang, Jung-Kuan ; Lin, Ching-Fuh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c428t-91a9d7d135892de1eaa0fbe1054e9a5333992b51cb6a6486a7e428f7ca6271193</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemistry</topic><topic>Film thickness</topic><topic>Fluorescence</topic><topic>Fourier transforms</topic><topic>Functional groups</topic><topic>Heavy metals</topic><topic>Luminous intensity</topic><topic>Rare earth elements</topic><topic>Resonance</topic><topic>Wavelengths</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lin, Yi-Shan</creatorcontrib><creatorcontrib>Tsai, Han-Yu</creatorcontrib><creatorcontrib>Huang, Jung-Kuan</creatorcontrib><creatorcontrib>Lin, Ching-Fuh</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lin, Yi-Shan</au><au>Tsai, Han-Yu</au><au>Huang, Jung-Kuan</au><au>Lin, Ching-Fuh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The relationship between basic group resonance and quantum yield of high efficiency red light fluorescent solutions</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2021-12-08</date><risdate>2021</risdate><volume>11</volume><issue>62</issue><spage>39142</spage><epage>39146</epage><pages>39142-39146</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Compared with rare earth elements and heavy metal elements, rare-earth-element-free fluorescent films can greatly reduce environmental hazards. In this study, we use a solution method to produce the fluorescent films. The film thickness is 10 μm, which can maintain fluorescent light intensity in an environment with an average humidity of 55.1 (RH%) after encapsulation. We also find that the type of solvent affects the resonance position of the C&z.tbd;N functional group in DCJTB at a wavenumber of 2196 (cm
−1
), measured with Fourier transform infrared spectroscopy. The functional group is affected by the polar effect with its displacement decreasing with the quantum yield. Finally, we successfully made a fluorescent solution with a resonance displacement of only 12.8 (cm
−1
) for the C&z.tbd;N functional group with the quantum yield being as high as 81.3% and a fluorescent film with a quantum yield as high as 84.8%.
The fluorescent solution with a resonance displacement of only 12.8 (cm
−1
) for the C&z.tbd;N functional group gives this film a quantum yield as high as 84.8%.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35492482</pmid><doi>10.1039/d1ra06326j</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-3787-2163</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Chemistry Film thickness Fluorescence Fourier transforms Functional groups Heavy metals Luminous intensity Rare earth elements Resonance Wavelengths |
title | The relationship between basic group resonance and quantum yield of high efficiency red light fluorescent solutions |
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