The relationship between basic group resonance and quantum yield of high efficiency red light fluorescent solutions

Compared with rare earth elements and heavy metal elements, rare-earth-element-free fluorescent films can greatly reduce environmental hazards. In this study, we use a solution method to produce the fluorescent films. The film thickness is 10 μm, which can maintain fluorescent light intensity in an...

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Veröffentlicht in:RSC advances 2021-12, Vol.11 (62), p.39142-39146
Hauptverfasser: Lin, Yi-Shan, Tsai, Han-Yu, Huang, Jung-Kuan, Lin, Ching-Fuh
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container_issue 62
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container_title RSC advances
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creator Lin, Yi-Shan
Tsai, Han-Yu
Huang, Jung-Kuan
Lin, Ching-Fuh
description Compared with rare earth elements and heavy metal elements, rare-earth-element-free fluorescent films can greatly reduce environmental hazards. In this study, we use a solution method to produce the fluorescent films. The film thickness is 10 μm, which can maintain fluorescent light intensity in an environment with an average humidity of 55.1 (RH%) after encapsulation. We also find that the type of solvent affects the resonance position of the C&z.tbd;N functional group in DCJTB at a wavenumber of 2196 (cm −1 ), measured with Fourier transform infrared spectroscopy. The functional group is affected by the polar effect with its displacement decreasing with the quantum yield. Finally, we successfully made a fluorescent solution with a resonance displacement of only 12.8 (cm −1 ) for the C&z.tbd;N functional group with the quantum yield being as high as 81.3% and a fluorescent film with a quantum yield as high as 84.8%. The fluorescent solution with a resonance displacement of only 12.8 (cm −1 ) for the C&z.tbd;N functional group gives this film a quantum yield as high as 84.8%.
doi_str_mv 10.1039/d1ra06326j
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subjects Chemistry
Film thickness
Fluorescence
Fourier transforms
Functional groups
Heavy metals
Luminous intensity
Rare earth elements
Resonance
Wavelengths
title The relationship between basic group resonance and quantum yield of high efficiency red light fluorescent solutions
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