The relationship between basic group resonance and quantum yield of high efficiency red light fluorescent solutions

Compared with rare earth elements and heavy metal elements, rare-earth-element-free fluorescent films can greatly reduce environmental hazards. In this study, we use a solution method to produce the fluorescent films. The film thickness is 10 μm, which can maintain fluorescent light intensity in an...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:RSC advances 2021-12, Vol.11 (62), p.39142-39146
Hauptverfasser: Lin, Yi-Shan, Tsai, Han-Yu, Huang, Jung-Kuan, Lin, Ching-Fuh
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Compared with rare earth elements and heavy metal elements, rare-earth-element-free fluorescent films can greatly reduce environmental hazards. In this study, we use a solution method to produce the fluorescent films. The film thickness is 10 μm, which can maintain fluorescent light intensity in an environment with an average humidity of 55.1 (RH%) after encapsulation. We also find that the type of solvent affects the resonance position of the C&z.tbd;N functional group in DCJTB at a wavenumber of 2196 (cm −1 ), measured with Fourier transform infrared spectroscopy. The functional group is affected by the polar effect with its displacement decreasing with the quantum yield. Finally, we successfully made a fluorescent solution with a resonance displacement of only 12.8 (cm −1 ) for the C&z.tbd;N functional group with the quantum yield being as high as 81.3% and a fluorescent film with a quantum yield as high as 84.8%. The fluorescent solution with a resonance displacement of only 12.8 (cm −1 ) for the C&z.tbd;N functional group gives this film a quantum yield as high as 84.8%.
ISSN:2046-2069
2046-2069
DOI:10.1039/d1ra06326j