Recent Progress in Luminous Particle‐Encapsulated Host–Guest Metal‐Organic Frameworks for Optical Applications

Metal‐organic frameworks (MOFs) as a unique class of porous crystalline materials have received comprehensive attention in the past decades. Among them, luminescent MOFs (LMOFs) have been a well‐known branch on account of their relevance as optical materials in contemporary era. The establishment of host–guest hybrid LMOF materials has triggered a hot search area owing to the extensive range of applications that can be adjusted by soliciting different functional luminescent guests. Current developments in the thought‐provoking application of host–guest LMOFs have stretched into far‐ranging fields, including light regulation, imaging, sensing, data encryption, etc. This review discusses on the hybridization of MOFs with functional luminescent particles (LPs) as guests for the construction of a series of extraordinary host–guest luminescent composite materials (LP@MOFs). The basic aspects, involving the preconcentration of MOF hosts and luminous guests as well as the comprehensive synthetic strategies of LP@MOFs are introduced. Furthermore, the applications of luminescent LP@MOF materials are highlighted, with a particular emphasis on the present and continuing challenges and the demand trends of such materials that need to be explored. The host–guest metal‐organic frameworks (MOFs) modified by the luminescent guests have shown great potential in optical applications. Here, the design and construction strategy of host–guest luminescent MOFs based on luminescent guest encapsulation are reviewed, and their optical applications in different fields such as chemical sensing, white light, laser, biological imaging and information anticounterfeiting are summarized.