Graphene's Role in Emerging Trends of Capacitive Energy Storage

Technological breakthroughs in energy storage are being driven by the development of next‐generation supercapacitors with favorable features besides high‐power density and cycling stability. In this innovation, graphene and its derived materials play an active role. Here, the research status of graphene supercapacitors is analyzed. Recent progress is outlined in graphene assembly, exfoliation, and processing techniques. In addition, electrochemical and electrical attributes that are increasingly valued in next‐generation supercapacitors are highlighted along with a summary of the latest research addressing chemical modification of graphene and its derivatives for future supercapacitors. The challenges and solutions discussed in the review hopefully will shed light on the commercialization of graphene and a broader genre of 2D materials in energy storage applications. Next‐generation supercapacitors with features beyond high‐power density and cycling stability are crucial for advancing energy storage technologies. This review analyzes the research status of graphene supercapacitors, highlighting attributes that are increasingly valued in the next‐generation devices, and summarizing the latest research addressing chemical modification of graphene and its derivatives for emerging capacitive energy storage applications.