Templating Synthesis of Metal–Organic Framework Nanofiber Aerogels and Their Derived Hollow Porous Carbon Nanofibers for Energy Storage and Conversion

A kind of metal–organic framework (MOF) aerogels are synthesized by the self‐assembly of uniform and monodisperse MOF nanofibers. Such MOF nanofiber aerogels as carbon precursors can effectively avoid the aggregation of nanofibers during calcination, resulting in the formation of well‐dispersed hollow porous carbon nanofibers (HPCNs). Moreover, HPCNs with well‐dispersion are investigated as sulfur host materials for Li–S batteries and electrocatalysts for cathode oxygen reduction reaction (ORR). On the one hand, HPCNs act as hosts for the encapsulation of sulfur into their hierarchical micro‐ and mesopores as well as hollow nanostructures. The obtained sulfur cathode exhibits excellent electrochemical features, good cycling stability and high coulombic efficiency. On the other hand, HPCNs exhibit better electrocatalytic activity than aggregated counterparts for ORR. Furthermore, a highly active single atom electrocatalyst can be prepared by the carbonization of bimetallic MOF nanofiber aerogels. The results indicate that well‐dispersed HPCNs show enhanced electrochemical properties in contrast to their aggregated counterparts, suggesting that the dispersion situation of nanomaterials significantly influence their final performance. The present concept of employing MOF nanofiber aerogels as precursors will provide a new strategy to the design of MOF‐derived nanomaterials with well‐dispersion for their applications in energy storage and conversion. A kind of metal–organic framework (MOF) nanofiber aerogels are synthesized by the self‐assembly of MOF nanofibers. Such nanofiber aerogels can be pyrolyzed to form well‐dispersed hollow porous carbon nanofibers, which show the enhanced electrochemical performance as sulfur host materials for Li–S batteries and single atom electrocatalysts for oxygen reduction reaction.