Enhanced dye-sensitized solar cell performance using strontium titanate perovskite integrated photoanodes modified with plasmonic silver nanoparticles

•Ag-SrTiO3NCs were prepared by a facile chemical reduction method and employed as photoanode of DSSC.•Surface plasmon resonance feature of Ag NPs improves light scattering in the Ag-SrTiO3 NC photoanode.•Reduced charge recombination and enhanced charge transfer in the Ag-SrTiO3 NC lead to improved D...

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Veröffentlicht in:Journal of alloys and compounds 2021-12, Vol.889, p.161693, Article 161693
Hauptverfasser: Sasikala, R., Kandasamy, M., Suresh, S., Ragavendran, V., Sasirekha, V., Pearce, J.M., Murugesan, S., Mayandi, J.
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Sprache:eng
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Zusammenfassung:•Ag-SrTiO3NCs were prepared by a facile chemical reduction method and employed as photoanode of DSSC.•Surface plasmon resonance feature of Ag NPs improves light scattering in the Ag-SrTiO3 NC photoanode.•Reduced charge recombination and enhanced charge transfer in the Ag-SrTiO3 NC lead to improved DSSC efficiency. [Display omitted] Plasmonic silver nanoparticles loaded strontium titanate nanocomposites (Ag-SrTiO3 NC) with diverse weight percentages (0.5, 1.5, 2.5 and 5 wt%) of Ag nanoparticles (Ag NPs) are synthesized by a facile chemical reduction method. The prepared nanocomposites are characterized using diffuse reflectance spectroscopy, X-ray diffractometry, photoluminescence spectroscopy, scanning electronic microscopy and transmission electron microscopy. The photovoltaic performance of dye-sensitized solar cells (DSSCs) integrated with Ag-SrTiO3 NC photoanodes has been assessed under simulated sun light intensity of 100 mW cm−2. The Ag-SrTiO3 NC photoanode loaded with 2.5 wt% Ag NPs exhibited higher power conversion efficiency of 4.39% with short-circuit photocurrent density of 11.54 mA cm−2, open circuit voltage of 0.77 V and fill factor of 0.49 in DSSC. This enhanced photovoltaic performance can be credited to high dye loading, improvement in visible light harvesting - and fast photo-induced electron transfer caused by the plasmonic Ag NPs.
ISSN:0925-8388
1873-4669
DOI:10.1016/j.jallcom.2021.161693