Unusual design strategy for a stable and soluble high-molecular-weight copper() arylacetylide polymer

Unusual design strategy for a stable and soluble high-molecular-weight copper() arylacetylide polymer

A long enough side chain, electron-withdrawing ester groups and a chloroform solvent in the polymerization can together relay solubility and/or stability to the copper( i ) arylacetylide polymer. The copper( i ) arylacetylide polymers reported previously are almost insoluble and infusible so as to r...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2021-11, Vol.57 (9), p.124-127
Hauptverfasser: Jiang, Li, Jia, Jiangtao, Zhai, Yongchang, Zhao, Zhiqiang, Chen, Yu, Cui, Fengchao, Tian, Yuyang, Zheng, Bian, Tian, Hongkun, Kang, Chuanqing, Gao, Lianxun, Eddaoudi, Mohamed, Guangshan, Zhu
Format: Artikel
Sprache:eng
Schlagworte:
Chloroform
Copper
Polymers
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Zusammenfassung:A long enough side chain, electron-withdrawing ester groups and a chloroform solvent in the polymerization can together relay solubility and/or stability to the copper( i ) arylacetylide polymer. The copper( i ) arylacetylide polymers reported previously are almost insoluble and infusible so as to restrain their applications. Herein, an unusual design strategy for stable and soluble copper( i ) arylacetylide polymers is reported.
ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc05080j