Electron-phonon coupling in the charge density wave state of CsV\(_3\)Sb\(_5\)

Metallic materials with kagome lattice structure are interesting because their electronic structures can host flat bands, Dirac cones, and van Hove singularities, resulting in strong electron correlations, nontrivial band topology, charge density wave (CDW), and unconventional superconductivity. Recently, kagome lattice compounds AV\(_3\)Sb\(_5\) (A = K, Rb, Cs) are found to have intertwined CDW order and superconductivity. The origin of the CDW has been suggested to be purely electronic, arising from Fermi-surface instabilities of van Hove singularity (saddle point) near the M points. Here we use neutron scattering experiments to demonstrate that the CDW order in CsV\(_3\)Sb\(_5\) is associated with static lattice distortion and a sudden hardening of the B3u longitudinal optical phonon mode, thus establishing that electron-phonon coupling must also play an important role in the CDW order of AV\(_3\)Sb\(_5\).