Pd/C-Catalyzed Hydrogenation of Substituted 5-Acyl-1,3-dioxanes

Pd/C-Catalyzed Hydrogenation of Substituted 5-Acyl-1,3-dioxanes

Hydrogenation of substituted 5-acyl-1,3-dioxanes in the presence of a Pd/C catalyst leads to the formation of substituted 1,3-dioxane alcohols as the only reaction products. The effect of a number of factors (temperature, rate of hydrogen and substrate supply) on the conversion of the ketone and the...

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Veröffentlicht in:Russian journal of general chemistry 2021-09, Vol.91 (9), p.1619-1622
Hauptverfasser: Borisova, Yu. G., Musin, A. I., Yakupov, N. V., Raskildina, G. Z., Daminev, R. R., Zlotskii, S. S.
Format: Artikel
Sprache:eng
Schlagworte:
Alcohols
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Dioxane
Hydrogenation
Reaction products
Selectivity
Substitutes
Substrates
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Zusammenfassung:Hydrogenation of substituted 5-acyl-1,3-dioxanes in the presence of a Pd/C catalyst leads to the formation of substituted 1,3-dioxane alcohols as the only reaction products. The effect of a number of factors (temperature, rate of hydrogen and substrate supply) on the conversion of the ketone and the selectivity of the formation of alcohol was investigated.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363221090036