Extraction of Palladium(II) with 4-[(Hexylsulfanyl)methyl]-3,5-dimethylisoxazole from Hydrochloric Acid Solutions
The extraction properties of the new extractant 4-[(hexylsulfanyl)methyl]-3,5-dimethylisoxazole have been studied under the conditions of palladium(II) extraction from hydrochloric acid solutions with toluene as a diluent. The extractant effectively extracts Pd(II) from 0.1–6 M HCl solutions with hi...
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| Veröffentlicht in: | Russian journal of general chemistry 2021-09, Vol.91 (9), p.1740-1747 |
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| container_title | Russian journal of general chemistry |
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| creator | Anpilogova, G. R. Baeva, L. A. Murinov, Yu. I. |
| description | The extraction properties of the new extractant 4-[(hexylsulfanyl)methyl]-3,5-dimethylisoxazole have been studied under the conditions of palladium(II) extraction from hydrochloric acid solutions with toluene as a diluent. The extractant effectively extracts Pd(II) from 0.1–6 M HCl solutions with high selectivity towards Pt(IV), Cu(II), Ni(II), Fe(III), and Al(III). The coordination mechanism of the Pd(II) extraction from 1 M HCl solutions with the formation of the extractable compound [Cl
2
Pd(μ-L)
2
PdCl
2
] has been established. The values of the concentration constant and thermodynamic parameters of the Pd(II) extraction from 1 M HCl solutions were estimated. Palladium(II) is quantitatively stripped with hydrochloric acid solution of thiourea. |
| doi_str_mv | 10.1134/S107036322109019X |
| format | Article |
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2
Pd(μ-L)
2
PdCl
2
] has been established. The values of the concentration constant and thermodynamic parameters of the Pd(II) extraction from 1 M HCl solutions were estimated. Palladium(II) is quantitatively stripped with hydrochloric acid solution of thiourea.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S107036322109019X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aluminum ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Copper ; Hydrochloric acid ; Hydrogen chloride ; Iron ; Nickel ; Palladium ; Selectivity ; Toluene</subject><ispartof>Russian journal of general chemistry, 2021-09, Vol.91 (9), p.1740-1747</ispartof><rights>Pleiades Publishing, Ltd. 2021</rights><rights>Pleiades Publishing, Ltd. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-705ae723218a856b3b74c8fd8a1019bef5bab6e032a2769b8aa7ea72379e9e733</citedby><cites>FETCH-LOGICAL-c316t-705ae723218a856b3b74c8fd8a1019bef5bab6e032a2769b8aa7ea72379e9e733</cites><orcidid>0000-0002-8199-1912 ; 0000-0001-6541-3285 ; 0000-0002-4475-8556</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S107036322109019X$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S107036322109019X$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Anpilogova, G. R.</creatorcontrib><creatorcontrib>Baeva, L. A.</creatorcontrib><creatorcontrib>Murinov, Yu. I.</creatorcontrib><title>Extraction of Palladium(II) with 4-[(Hexylsulfanyl)methyl]-3,5-dimethylisoxazole from Hydrochloric Acid Solutions</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>The extraction properties of the new extractant 4-[(hexylsulfanyl)methyl]-3,5-dimethylisoxazole have been studied under the conditions of palladium(II) extraction from hydrochloric acid solutions with toluene as a diluent. The extractant effectively extracts Pd(II) from 0.1–6 M HCl solutions with high selectivity towards Pt(IV), Cu(II), Ni(II), Fe(III), and Al(III). The coordination mechanism of the Pd(II) extraction from 1 M HCl solutions with the formation of the extractable compound [Cl
2
Pd(μ-L)
2
PdCl
2
] has been established. The values of the concentration constant and thermodynamic parameters of the Pd(II) extraction from 1 M HCl solutions were estimated. Palladium(II) is quantitatively stripped with hydrochloric acid solution of thiourea.</description><subject>Aluminum</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Copper</subject><subject>Hydrochloric acid</subject><subject>Hydrogen chloride</subject><subject>Iron</subject><subject>Nickel</subject><subject>Palladium</subject><subject>Selectivity</subject><subject>Toluene</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1UFtLwzAULqLgnP4A3wK-TDCay5qkj2NMNxgoTEEQKWmbuoy02ZIWV3-9GRV8EJ_OOXw3zhdFlxjdYkzHdyuMOKKMEoJRgnDyehQNMEMCUhqj47AHGB7w0-jM-w1CGCFGBtFutm-czBtta2BL8CSNkYVuq9FicQ0-dbMGY_g2mqt9Z3xrSll35rpSzboz75DexLDQ_aW93csvaxQona3AvCuczdfGOp2DSa4LsLKmPaT48-iklMari585jF7uZ8_TOVw-PiymkyXMKWYN5CiWihNKsJAiZhnN-DgXZSEkDu9lqowzmTGFKJGEsyQTUnIlg4AnKlGc0mF01ftund21yjfpxrauDpEpiQVHTDCOAwv3rNxZ750q063TlXRdilF6aDb902zQkF7jA7f-UO7X-X_RNxgpeyM</recordid><startdate>20210901</startdate><enddate>20210901</enddate><creator>Anpilogova, G. R.</creator><creator>Baeva, L. A.</creator><creator>Murinov, Yu. I.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-8199-1912</orcidid><orcidid>https://orcid.org/0000-0001-6541-3285</orcidid><orcidid>https://orcid.org/0000-0002-4475-8556</orcidid></search><sort><creationdate>20210901</creationdate><title>Extraction of Palladium(II) with 4-[(Hexylsulfanyl)methyl]-3,5-dimethylisoxazole from Hydrochloric Acid Solutions</title><author>Anpilogova, G. R. ; Baeva, L. A. ; Murinov, Yu. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-705ae723218a856b3b74c8fd8a1019bef5bab6e032a2769b8aa7ea72379e9e733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Aluminum</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Copper</topic><topic>Hydrochloric acid</topic><topic>Hydrogen chloride</topic><topic>Iron</topic><topic>Nickel</topic><topic>Palladium</topic><topic>Selectivity</topic><topic>Toluene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Anpilogova, G. R.</creatorcontrib><creatorcontrib>Baeva, L. A.</creatorcontrib><creatorcontrib>Murinov, Yu. I.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Anpilogova, G. R.</au><au>Baeva, L. A.</au><au>Murinov, Yu. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Extraction of Palladium(II) with 4-[(Hexylsulfanyl)methyl]-3,5-dimethylisoxazole from Hydrochloric Acid Solutions</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2021-09-01</date><risdate>2021</risdate><volume>91</volume><issue>9</issue><spage>1740</spage><epage>1747</epage><pages>1740-1747</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>The extraction properties of the new extractant 4-[(hexylsulfanyl)methyl]-3,5-dimethylisoxazole have been studied under the conditions of palladium(II) extraction from hydrochloric acid solutions with toluene as a diluent. The extractant effectively extracts Pd(II) from 0.1–6 M HCl solutions with high selectivity towards Pt(IV), Cu(II), Ni(II), Fe(III), and Al(III). The coordination mechanism of the Pd(II) extraction from 1 M HCl solutions with the formation of the extractable compound [Cl
2
Pd(μ-L)
2
PdCl
2
] has been established. The values of the concentration constant and thermodynamic parameters of the Pd(II) extraction from 1 M HCl solutions were estimated. Palladium(II) is quantitatively stripped with hydrochloric acid solution of thiourea.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S107036322109019X</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-8199-1912</orcidid><orcidid>https://orcid.org/0000-0001-6541-3285</orcidid><orcidid>https://orcid.org/0000-0002-4475-8556</orcidid></addata></record> |
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| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Aluminum Chemistry Chemistry and Materials Science Chemistry/Food Science Copper Hydrochloric acid Hydrogen chloride Iron Nickel Palladium Selectivity Toluene |
| title | Extraction of Palladium(II) with 4-[(Hexylsulfanyl)methyl]-3,5-dimethylisoxazole from Hydrochloric Acid Solutions |
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