Synthesis and copolymerization of new methacrylic monomers for the creation of nonlinear optical polymer materials

A new methacrylic monomer, 3,5-bis[2-( N -ethylanilino)ethoxy]benzyl methacrylate (MBA), has been synthesized. Methacrylic copolymers with different content of bi-chromophore fragments in the side chain were obtained by radical copolymerization of methyl methacrylate and MBA, followed by azo-functio...

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Veröffentlicht in:	Russian chemical bulletin 2021-09, Vol.70 (9), p.1757-1764
Hauptverfasser:	Gaisin, A. I., Vakhonina, T. A., Mukhtarov, A. Sh, Shmelev, A. G., Balakina, M. Yu
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical synthesis Chemistry Chemistry and Materials Science Chemistry/Food Science Chromophores Copolymerization Copolymers Full Articles Inorganic Chemistry Monomers Nonlinear optics Optical properties Organic Chemistry Polymethyl methacrylate Spin coating Thermodynamic properties Thin films
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Beschreibung
Zusammenfassung:	A new methacrylic monomer, 3,5-bis[2-( N -ethylanilino)ethoxy]benzyl methacrylate (MBA), has been synthesized. Methacrylic copolymers with different content of bi-chromophore fragments in the side chain were obtained by radical copolymerization of methyl methacrylate and MBA, followed by azo-functionalization reaction. The composition of the obtained copolymers was established, and their thermal properties were determined. Thin films of synthesized copolymers were prepared by spin-coating and the nonlinear optical characteristics of the obtained materials were investigated.
ISSN:	1066-5285 1573-9171
DOI:	10.1007/s11172-021-3280-6