Quenching-induced nonergodicity in ergodic Na1/2Bi1/2TiO3–BaTiO3–AgNbO3 ceramics

Quenching from sintering temperature enhances the depolarization temperature ( T d ) in Na 1/2 Bi 1/2 TiO 3 -based ceramics without significant deterioration of piezoelectric properties ( d 33 ). In this work, quenching effects in an ergodic relaxor 0.97(0.94Na 0.5 Bi 0.5 TiO 3 –0.06BaTiO 3 )–0.03AgNbO 3 (NBT–6BT–3AN) were investigated based on structure, ferroelectric, and dielectric properties. The ergodicity to nonergodicity transition was obtained by quenching NBT–6BT–3AN above 1000 °C. The temperature stability of the quenching-induced nonergodicity was examined by annealing the quenched sample at 300 °C and 600 °C. The effect of oxygen vacancy on ergodicity to nonergodicity transition was investigated by comparing ferroelectric and electrostrain responses of the quenched and nitrogen-atmosphere-annealed samples. The influence of quenching on the structure including the average crystal structure, phase fraction and lattice distortion and the local structure including bond lengths and ordering of ions was analyzed. The ergodicity to nonergodicity transition upon quenching is ascribed to the contribution of the off-centered Bi 3+ ions and ordered local structure. Graphical abstract