X-ray photoelectron study of Si+ ion implanted polymers

X-ray photoelectron spectroscopy was used to characterize different polymer materials implanted with low energy Si+ ions (E=30 keV, D= 1.1017 cm−2). Two kinds of polymers were studied – ultra-high-molecular-weight poly-ethylene (UHMWPE), and poly-methyl-methacrylate (PMMA). The non-implanted polymer...

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Veröffentlicht in:Journal of physics. Conference series 2010-11, Vol.253 (1), p.012070
Hauptverfasser: Tsvetkova, T, Balabanov, S, Bischoff, L, Krastev, V, Stefanov, P, Avramova, I
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creator Tsvetkova, T
Balabanov, S
Bischoff, L
Krastev, V
Stefanov, P
Avramova, I
description X-ray photoelectron spectroscopy was used to characterize different polymer materials implanted with low energy Si+ ions (E=30 keV, D= 1.1017 cm−2). Two kinds of polymers were studied – ultra-high-molecular-weight poly-ethylene (UHMWPE), and poly-methyl-methacrylate (PMMA). The non-implanted polymer materials show the expected variety of chemical bonds: carbon-carbon, carbon being three- and fourfold coordinated, and carbon-oxygen in the case of PMMA samples. The X-ray photoelectron and Raman spectra show that Si+ ion implantation leads to the introduction of additional disorder in the polymer material. The X-ray photoelectron spectra of the implanted polymers show that, in addition to already mentioned bonds, silicon creates new bonds with the host elements – Si-C and Si-O, together with additional Si dangling bonds as revealed by the valence band study of the implanted polymer materials.
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subjects Addition polymerization
Carbon
Chemical bonds
Ion implantation
Photoelectrons
Physics
Polyethylenes
Polymers
Polymethyl methacrylate
Raman spectra
Silicon
Spectrum analysis
Valence band
X ray spectra
title X-ray photoelectron study of Si+ ion implanted polymers
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