Synthesis of Terminal N‐Vinylazoles from Aromatic Aldehydes, DMSO, and Azoles Based DMSO as Terminal Carbon Synthon

Synthesis of Terminal N‐Vinylazoles from Aromatic Aldehydes, DMSO, and Azoles Based DMSO as Terminal Carbon Synthon

A protocol for the synthesis of terminal N‐vinylazoles from aromatic aldehydes, DMSO, and azoles has been reported. In this strategy, DMSO was involved in the construction of the C=C bond as a terminal carbon synthon. Both aromatic aldehydes and azoles could be well tolerated and give the correspond...

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Veröffentlicht in:Advanced synthesis & catalysis 2021-10, Vol.363 (19), p.4621-4626
Hauptverfasser: Nie, Zhiwen, Lv, Huifang, Li, Hui, Su, Miaodong, Yang, Tonglin, Luo, Weiping, Liu, Qiang, Guo, Cancheng
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Sprache:eng
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Aldehydes
Aromatic Aldehydes
Azoles
C=C and C−N bonds Formation
Carbon
DMSO
Heterocyclic compounds
Synthesis
Terminal N-vinylazoles
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container_end_page 4626
container_issue 19
container_start_page 4621
container_title Advanced synthesis & catalysis
container_volume 363
creator Nie, Zhiwen
Lv, Huifang
Li, Hui
Su, Miaodong
Yang, Tonglin
Luo, Weiping
Liu, Qiang
Guo, Cancheng
description A protocol for the synthesis of terminal N‐vinylazoles from aromatic aldehydes, DMSO, and azoles has been reported. In this strategy, DMSO was involved in the construction of the C=C bond as a terminal carbon synthon. Both aromatic aldehydes and azoles could be well tolerated and give the corresponding terminal N‐vinylazoles in 52–91% yields. Based on preliminary experiments, a plausible mechanism is proposed.
doi_str_mv 10.1002/adsc.202100663
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source Wiley Online Library Journals Frontfile Complete
subjects Aldehydes
Aromatic Aldehydes
Azoles
C=C and C−N bonds Formation
Carbon
DMSO
Heterocyclic compounds
Synthesis
Terminal N-vinylazoles
title Synthesis of Terminal N‐Vinylazoles from Aromatic Aldehydes, DMSO, and Azoles Based DMSO as Terminal Carbon Synthon
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