XAFS and XRD studies of local structure peculiarities in magnetic R2Fe17−xMnx (R Ce, Lu) intermetallics

The rearrangement of cerium and lutetium local environment in Ce2Fe17−xMnx and Lu2Fe17-xMnx intermetallics vs. Mn concentration and temperature was investigated by means of the extended X-ray absorption fine structure (EXAFS) spectroscopy above K-Ce absorption edge and powder X-ray diffraction. The...

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Veröffentlicht in:Journal of physics. Conference series 2013-04, Vol.430 (1)
Hauptverfasser: Menushenkov, A P, Yaroslavtsev, A A, Grishina, O V, Zaluzhnyy, I A, Chernikov, R V, Kuchin, A G
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Sprache:eng
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Zusammenfassung:The rearrangement of cerium and lutetium local environment in Ce2Fe17−xMnx and Lu2Fe17-xMnx intermetallics vs. Mn concentration and temperature was investigated by means of the extended X-ray absorption fine structure (EXAFS) spectroscopy above K-Ce absorption edge and powder X-ray diffraction. The valence state of Ce in Ce2Fe17−xMnx was also studied by X-ray absorption near-edge structure (XANES) spectroscopy above L3-Ce absorption edge. The correlation between changes in local electronic and crystal structure and the types of magnetic ordering in these compounds is discussed.
ISSN:1742-6588
1742-6596
DOI:10.1088/1742-6596/430/1/012104