Fe2N stabilized on reduced graphene oxide to enhance the performance of a lithium-ion battery composite anode

•Fe2N/rGO composites are obtained by altering the nitriding time.•The optimal Fe2N/rGO-2h composite exhibit capacity of 603 mAh g1 after 500 cycles.•A fading rate of only 0.014% is retained at a current density of 0.1 A g1.•The superior cyclability is due to flexible rGO framework and firm synergy with Fe2N.•This work can offer new insight to expand metal nitride as high efficacy electrode. [Display omitted] Fe2N decorated on reduced graphene oxide (rGO) was prepared by a hydrothermal reaction and the effect of nitridation time was studied concerning the lithium-ion battery (LIB) performance of Fe2N/rGO composites. The reversible capacity of as-prepared electrodes was evaluated at currents starting from 0.05 A g1 and up to 2 A g1 with the highest capacity demonstrated by the Fe2N/rGO sample subjected to a nitriding time of 2 h. Moreover, at 0.1 A g1 the specific capacity fading was observed to be merely 0.014% per cycle from 120 to 500 cycles. The CV studies demonstrated that good electrochemical performance was due to a smaller peak to peak separation and higher peak currents which agreed well with the lower mass and charge transfer resistance obtained from the EIS results. The conductive graphene network facilitated in Li+-ion diffusion process and fast charge transfer reactions while mesoporous Fe2N helped in proper penetration of electrolyte and providing abundant sites for intercalation/deintercalation. The Fe2N/rGO-2h electrode prepared in this work overcame the stability issues and large polarization of usual metal nitride electrodes making it a potential candidate for LIB anode.