Metal–Organic Frameworks of Magnesium Based on 2,5-Dihydroxy-3,6-di-tert-butyl-para-benzoquinone
New one-dimensional metal−organic frameworks of magnesium [Mg(pQ)·2DMF] n ( I ), [Mg(pQ)·2DMAA] n ( II ), and [Mg(pQ)·2(NMP)] n ( III ) (pQ is the 2,5-dihydroxy-3,6-di- tert -butyl- para -benzoquinone dianion) are synthesized by the solvothermal method in different solvents ( N , N -dimethylformamid...
Gespeichert in:
Veröffentlicht in: | Russian journal of coordination chemistry 2021-09, Vol.47 (9), p.610-619 |
---|---|
Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | New one-dimensional metal−organic frameworks of magnesium [Mg(pQ)·2DMF]
n
(
I
), [Mg(pQ)·2DMAA]
n
(
II
), and [Mg(pQ)·2(NMP)]
n
(
III
) (pQ is the 2,5-dihydroxy-3,6-di-
tert
-butyl-
para
-benzoquinone dianion) are synthesized by the solvothermal method in different solvents (
N
,
N
-dimethylformamide (DMF),
N
,
N
-dimethylacetamide (DMAA), and
N
-methyl-2-pyrrolidone (NMP)). The crystal structures of compounds
I
and
III
are determined by X-ray structure analysis (CIF files CCDC nos. 2058147 (
I
) and 2058148 (
II
)). The spectral characteristics and thermal stability of the synthesized metal−organic frameworks are studied. |
---|---|
ISSN: | 1070-3284 1608-3318 |
DOI: | 10.1134/S1070328421090086 |