Metal–Organic Frameworks of Magnesium Based on 2,5-Dihydroxy-3,6-di-tert-butyl-para-benzoquinone

New one-dimensional metal−organic frameworks of magnesium [Mg(pQ)·2DMF] n ( I ), [Mg(pQ)·2DMAA] n ( II ), and [Mg(pQ)·2(NMP)] n ( III ) (pQ is the 2,5-dihydroxy-3,6-di- tert -butyl- para -benzoquinone dianion) are synthesized by the solvothermal method in different solvents ( N , N -dimethylformamid...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Russian journal of coordination chemistry 2021-09, Vol.47 (9), p.610-619
Hauptverfasser: Trofimova, O. Yu, Ershova, I. V., Maleeva, A. V., Yakushev, I. A., Dorovatovskii, P. V., Aisin, R. R., Piskunov, A. V.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:New one-dimensional metal−organic frameworks of magnesium [Mg(pQ)·2DMF] n ( I ), [Mg(pQ)·2DMAA] n ( II ), and [Mg(pQ)·2(NMP)] n ( III ) (pQ is the 2,5-dihydroxy-3,6-di- tert -butyl- para -benzoquinone dianion) are synthesized by the solvothermal method in different solvents ( N , N -dimethylformamide (DMF), N , N -dimethylacetamide (DMAA), and N -methyl-2-pyrrolidone (NMP)). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files CCDC nos. 2058147 ( I ) and 2058148 ( II )). The spectral characteristics and thermal stability of the synthesized metal−organic frameworks are studied.
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328421090086