Linking dynamics and structure in highly asymmetric ionic liquids
We explore an idealized theoretical model for the transport of ions within highly asymmetric ionic liquid mixtures. A primitive model (PM)-inspired system serves as a representative for asymmetric ionic materials (such as liquid crystalline salts) which quench to form disordered, partially-arrested...
Gespeichert in:
| Veröffentlicht in: | arXiv.org 2021-08 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | |
| container_start_page | |
| container_title | arXiv.org |
| container_volume | |
| creator | Farías-Anguiano, Mariana E Cortés-Morales, Ernesto C Whitmer, Jonathan K Ramírez-González, Pedro E |
| description | We explore an idealized theoretical model for the transport of ions within highly asymmetric ionic liquid mixtures. A primitive model (PM)-inspired system serves as a representative for asymmetric ionic materials (such as liquid crystalline salts) which quench to form disordered, partially-arrested phases. Self-Consistent Generalized Langevin Equation (SCGLE) Theory is applied to understand the connection between the size ratio of charge-matched salts and their average mobility. Within this model, we identify novel glassy states where one of the two charged species (either the macro-cation or the micro-anion) are arrested, while the other retains mobility. We discuss how this result is useful in the development of novel single-ion conducting phases in ionic liquid based materials. |
| format | Article |
| fullrecord | <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_journals_2567813827</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2567813827</sourcerecordid><originalsourceid>FETCH-proquest_journals_25678138273</originalsourceid><addsrcrecordid>eNqNirsOgjAUQBsTE4nyD02cSeBWHqsxGgdHd9JAhYv0Ir3twN_L4Ae4nDOcsxERKJUl1QlgJ2LmIU1TKErIcxWJ8wPpjdTJdiFtsWGpqZXsXWh8cEYiyR67flyk5sVa4x02EidaOeIcsOWD2L70yCb-eS-Ot-vzck8-bpqDYV8PU3C0phryoqwyVUGp_ru-wjs6Fw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2567813827</pqid></control><display><type>article</type><title>Linking dynamics and structure in highly asymmetric ionic liquids</title><source>Free E- Journals</source><creator>Farías-Anguiano, Mariana E ; Cortés-Morales, Ernesto C ; Whitmer, Jonathan K ; Ramírez-González, Pedro E</creator><creatorcontrib>Farías-Anguiano, Mariana E ; Cortés-Morales, Ernesto C ; Whitmer, Jonathan K ; Ramírez-González, Pedro E</creatorcontrib><description>We explore an idealized theoretical model for the transport of ions within highly asymmetric ionic liquid mixtures. A primitive model (PM)-inspired system serves as a representative for asymmetric ionic materials (such as liquid crystalline salts) which quench to form disordered, partially-arrested phases. Self-Consistent Generalized Langevin Equation (SCGLE) Theory is applied to understand the connection between the size ratio of charge-matched salts and their average mobility. Within this model, we identify novel glassy states where one of the two charged species (either the macro-cation or the micro-anion) are arrested, while the other retains mobility. We discuss how this result is useful in the development of novel single-ion conducting phases in ionic liquid based materials.</description><identifier>EISSN: 2331-8422</identifier><language>eng</language><publisher>Ithaca: Cornell University Library, arXiv.org</publisher><subject>Asymmetry ; Ionic liquids ; Ions ; Liquid crystals</subject><ispartof>arXiv.org, 2021-08</ispartof><rights>2021. This work is published under http://arxiv.org/licenses/nonexclusive-distrib/1.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>780,784</link.rule.ids></links><search><creatorcontrib>Farías-Anguiano, Mariana E</creatorcontrib><creatorcontrib>Cortés-Morales, Ernesto C</creatorcontrib><creatorcontrib>Whitmer, Jonathan K</creatorcontrib><creatorcontrib>Ramírez-González, Pedro E</creatorcontrib><title>Linking dynamics and structure in highly asymmetric ionic liquids</title><title>arXiv.org</title><description>We explore an idealized theoretical model for the transport of ions within highly asymmetric ionic liquid mixtures. A primitive model (PM)-inspired system serves as a representative for asymmetric ionic materials (such as liquid crystalline salts) which quench to form disordered, partially-arrested phases. Self-Consistent Generalized Langevin Equation (SCGLE) Theory is applied to understand the connection between the size ratio of charge-matched salts and their average mobility. Within this model, we identify novel glassy states where one of the two charged species (either the macro-cation or the micro-anion) are arrested, while the other retains mobility. We discuss how this result is useful in the development of novel single-ion conducting phases in ionic liquid based materials.</description><subject>Asymmetry</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Liquid crystals</subject><issn>2331-8422</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqNirsOgjAUQBsTE4nyD02cSeBWHqsxGgdHd9JAhYv0Ir3twN_L4Ae4nDOcsxERKJUl1QlgJ2LmIU1TKErIcxWJ8wPpjdTJdiFtsWGpqZXsXWh8cEYiyR67flyk5sVa4x02EidaOeIcsOWD2L70yCb-eS-Ot-vzck8-bpqDYV8PU3C0phryoqwyVUGp_ru-wjs6Fw</recordid><startdate>20210827</startdate><enddate>20210827</enddate><creator>Farías-Anguiano, Mariana E</creator><creator>Cortés-Morales, Ernesto C</creator><creator>Whitmer, Jonathan K</creator><creator>Ramírez-González, Pedro E</creator><general>Cornell University Library, arXiv.org</general><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>L6V</scope><scope>M7S</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20210827</creationdate><title>Linking dynamics and structure in highly asymmetric ionic liquids</title><author>Farías-Anguiano, Mariana E ; Cortés-Morales, Ernesto C ; Whitmer, Jonathan K ; Ramírez-González, Pedro E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_journals_25678138273</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Asymmetry</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Liquid crystals</topic><toplevel>online_resources</toplevel><creatorcontrib>Farías-Anguiano, Mariana E</creatorcontrib><creatorcontrib>Cortés-Morales, Ernesto C</creatorcontrib><creatorcontrib>Whitmer, Jonathan K</creatorcontrib><creatorcontrib>Ramírez-González, Pedro E</creatorcontrib><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Farías-Anguiano, Mariana E</au><au>Cortés-Morales, Ernesto C</au><au>Whitmer, Jonathan K</au><au>Ramírez-González, Pedro E</au><format>book</format><genre>document</genre><ristype>GEN</ristype><atitle>Linking dynamics and structure in highly asymmetric ionic liquids</atitle><jtitle>arXiv.org</jtitle><date>2021-08-27</date><risdate>2021</risdate><eissn>2331-8422</eissn><abstract>We explore an idealized theoretical model for the transport of ions within highly asymmetric ionic liquid mixtures. A primitive model (PM)-inspired system serves as a representative for asymmetric ionic materials (such as liquid crystalline salts) which quench to form disordered, partially-arrested phases. Self-Consistent Generalized Langevin Equation (SCGLE) Theory is applied to understand the connection between the size ratio of charge-matched salts and their average mobility. Within this model, we identify novel glassy states where one of the two charged species (either the macro-cation or the micro-anion) are arrested, while the other retains mobility. We discuss how this result is useful in the development of novel single-ion conducting phases in ionic liquid based materials.</abstract><cop>Ithaca</cop><pub>Cornell University Library, arXiv.org</pub><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | EISSN: 2331-8422 |
| ispartof | arXiv.org, 2021-08 |
| issn | 2331-8422 |
| language | eng |
| recordid | cdi_proquest_journals_2567813827 |
| source | Free E- Journals |
| subjects | Asymmetry Ionic liquids Ions Liquid crystals |
| title | Linking dynamics and structure in highly asymmetric ionic liquids |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T02%3A35%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:book&rft.genre=document&rft.atitle=Linking%20dynamics%20and%20structure%20in%20highly%20asymmetric%20ionic%20liquids&rft.jtitle=arXiv.org&rft.au=Far%C3%ADas-Anguiano,%20Mariana%20E&rft.date=2021-08-27&rft.eissn=2331-8422&rft_id=info:doi/&rft_dat=%3Cproquest%3E2567813827%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2567813827&rft_id=info:pmid/&rfr_iscdi=true |