Constraining the Spatial Distribution of Tritium in Groundwater Across South Africa

Tritium (3H) has become synonymous with modern groundwater and is used in a myriad of applications, ranging from sustainability investigations to contaminant transport and groundwater vulnerability. This study uses measured 3H groundwater activities from 722 sample locations across South Africa to construct a 3H groundwater distribution surface. Environmental covariables are tested using geostatistical analysis to constrain external controls on 3H variability, namely: (a) depth to groundwater, (b) distance from the ocean, and (c) summer versus winter rainfall proportion. The inclusion of covariables in the “fit” of residual variograms improved prediction variance significantly yet does not mitigate issues with sample density. The distribution of 3H in groundwater agrees well to expected controls, with proximal (