The mechanism of radiolysis of alkaline-earth nitrates

The mechanism of radiolysis of alkaline-earth nitrates

The formation of peroxynitrite and nitrite in crystalline alkaline-earth nitrates under γ-irradiation at 310 K by optical reflectance spectroscopy has been studied. The radiolysis of Sr(NO3)2 and Ba(NO3)2 results in nitrite and peroxynitrite, Mg(NO3)2·6H2O and Ca(NO3)2·4H2O - nitrite. The mechanism...

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Veröffentlicht in:IOP conference series. Materials Science and Engineering 2015-04, Vol.80 (1), p.12023
Hauptverfasser: Anan'ev, V, Kriger, L, Miklin, M
Format: Artikel
Sprache:eng
Schlagworte:
Crystal structure
Crystallinity
Earth
Formations
Gamma irradiation
Nitrates
Nitrites
Radiolysis
Reflectance
Reflectivity
Spectroscopy
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Zusammenfassung:The formation of peroxynitrite and nitrite in crystalline alkaline-earth nitrates under γ-irradiation at 310 K by optical reflectance spectroscopy has been studied. The radiolysis of Sr(NO3)2 and Ba(NO3)2 results in nitrite and peroxynitrite, Mg(NO3)2·6H2O and Ca(NO3)2·4H2O - nitrite. The mechanism for nitrite and peroxynitrite formation under γ-irradiation of crystalline alkaline-earth nitrates has been discussed.
ISSN:1757-8981
1757-899X
1757-899X
DOI:10.1088/1757-899X/80/1/012023