Programmable Chromism and Photoluminescence of Spiropyran‐Based Liquid Crystalline Polymer with Tunable Glass Transition Temperature

Spiropyran‐based materials (SPBMs) can give responses to the stimulations induced by the light, heat, force, or pH, which have been used as triggers for many smart materials. Here, a cross‐linkable SPBM containing mesogenic‐units is synthesized, which is pale‐colored, non‐photoluminescent and non‐mesogenic at a spiro form, but dark‐colored, photoluminescent, and mesogenic at a merocyanine form. Moreover, the dynamic interconversion behavior of the form in the different chemical environments are distinct. Liquid crystalline polymers (LCPs) containing the SPBMs cross‐linked via visible light, own a photoswitchable glass transition temperature (Tg) and retain the switchable property; however, the SPBMs cross‐linked via UV light will be locked at the MC state, because the molecular movement was frozen at the room temperature lower than the given Tg of the LCP. Thus, programmable chromism and photoluminescence based on the tunable Tg can be endowed to the functional materials prepared from the SPBMs. A cross‐linkable spiropyran‐based molecule (SPBM) containing mesogenic units with switchable color, photoluminescence and mesomorphism is synthesized. Therefore, programmable chromism and photoluminescence can be endowed to the functional materials prepared from the SPBMs, which own a tunable glass transition temperature (Tg) by converting the configuration of the crosslinked SPBMs to change the molecular order degree.