Template Synthesis for Disilamacrocycles via Ring-closing Metathesis

Template Synthesis for Disilamacrocycles via Ring-closing Metathesis

A facile and novel template synthesis of flexible disilamacrocyclic compounds via a ring-closing metathesis coupling was achieved. The structures of the macrocycles were determined by X-ray crystallography, and two conformers with similar stabilization energies were observed and characterized.

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Veröffentlicht in:Chemistry letters 2021-07, Vol.50 (7), p.1397-1399
Hauptverfasser: Tu, Yuyang, Inagaki, Yusuke, Kwon, Eunsang, Setaka, Wataru
Format: Artikel
Sprache:eng
Schlagworte:
Coupling (molecular)
Crystallography
Metathesis
Synthesis
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Beschreibung
Zusammenfassung:A facile and novel template synthesis of flexible disilamacrocyclic compounds via a ring-closing metathesis coupling was achieved. The structures of the macrocycles were determined by X-ray crystallography, and two conformers with similar stabilization energies were observed and characterized.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.210234