Polymorphic donor–acceptor substituted chalcone: structural, spectral, dielectric and nonlinear optical properties for optical limiting applications
Herein, we report the third-order nonlinear absorption and optical limiting property of fluorinated polymorphic nonlinear optical (NLO) material 1-(3,4-dimethoxyphenyl)-3-(4-fluorophenyl) prop-2-en-1-one (abbreviated as PDPFO) based on reverse saturable absorption. The FTIR studies of optically tran...
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Veröffentlicht in: | Chemical papers 2021-09, Vol.75 (9), p.4749-4758 |
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creator | Raghavendra, S. Kumar, C. S. Chidan Kumar, D. J. Madhu Al-Ghorbani, Mohammed Alsalme, Ali Quah, C. K. Raghavendra, P. V. Serrao, Felcy Jyothi Dharmaprakash, S. M. |
description | Herein, we report the third-order nonlinear absorption and optical limiting property of fluorinated polymorphic nonlinear optical (NLO) material 1-(3,4-dimethoxyphenyl)-3-(4-fluorophenyl) prop-2-en-1-one (abbreviated as PDPFO) based on reverse saturable absorption. The FTIR studies of optically transparent PDPFO single crystals confirm the presence of various functional groups. PDPFO is optically transparent in the visible wavelength region. The open aperture Z-scan technique showed the intensity-dependent nonlinear absorption
.
A decrease in normalized transmittance with input intensity indicated the optical limiting behavior at the wavelength 532 nm. The excited-state absorption cross-section value (
σ
ex
=
1.72 × 10
–16
cm
2
) is much greater than ground-state absorption cross-section value
(
σ
g
=
2.49 × 10
–22
cm
2
), suggesting that optical limiting phenomena are due to RSA. |
doi_str_mv | 10.1007/s11696-021-01705-9 |
format | Article |
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.
A decrease in normalized transmittance with input intensity indicated the optical limiting behavior at the wavelength 532 nm. The excited-state absorption cross-section value (
σ
ex
=
1.72 × 10
–16
cm
2
) is much greater than ground-state absorption cross-section value
(
σ
g
=
2.49 × 10
–22
cm
2
), suggesting that optical limiting phenomena are due to RSA.</description><identifier>ISSN: 2585-7290</identifier><identifier>ISSN: 0366-6352</identifier><identifier>EISSN: 1336-9075</identifier><identifier>DOI: 10.1007/s11696-021-01705-9</identifier><language>eng</language><publisher>Warsaw: Versita</publisher><subject>Absorption cross sections ; Biochemistry ; Biotechnology ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Constraining ; Functional groups ; Industrial Chemistry/Chemical Engineering ; Materials Science ; Medicinal Chemistry ; Nonlinear optics ; Optical properties ; Original Paper ; Single crystals</subject><ispartof>Chemical papers, 2021-09, Vol.75 (9), p.4749-4758</ispartof><rights>Institute of Chemistry, Slovak Academy of Sciences 2021</rights><rights>Institute of Chemistry, Slovak Academy of Sciences 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c270t-63642cef6e9d6ed7e9ba648370a6dc367ffa63e23691e2308e4a27f515226ddd3</cites><orcidid>0000-0002-9633-953X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11696-021-01705-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11696-021-01705-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Raghavendra, S.</creatorcontrib><creatorcontrib>Kumar, C. S. Chidan</creatorcontrib><creatorcontrib>Kumar, D. J. Madhu</creatorcontrib><creatorcontrib>Al-Ghorbani, Mohammed</creatorcontrib><creatorcontrib>Alsalme, Ali</creatorcontrib><creatorcontrib>Quah, C. K.</creatorcontrib><creatorcontrib>Raghavendra, P. V.</creatorcontrib><creatorcontrib>Serrao, Felcy Jyothi</creatorcontrib><creatorcontrib>Dharmaprakash, S. M.</creatorcontrib><title>Polymorphic donor–acceptor substituted chalcone: structural, spectral, dielectric and nonlinear optical properties for optical limiting applications</title><title>Chemical papers</title><addtitle>Chem. Pap</addtitle><description>Herein, we report the third-order nonlinear absorption and optical limiting property of fluorinated polymorphic nonlinear optical (NLO) material 1-(3,4-dimethoxyphenyl)-3-(4-fluorophenyl) prop-2-en-1-one (abbreviated as PDPFO) based on reverse saturable absorption. The FTIR studies of optically transparent PDPFO single crystals confirm the presence of various functional groups. PDPFO is optically transparent in the visible wavelength region. The open aperture Z-scan technique showed the intensity-dependent nonlinear absorption
.
A decrease in normalized transmittance with input intensity indicated the optical limiting behavior at the wavelength 532 nm. The excited-state absorption cross-section value (
σ
ex
=
1.72 × 10
–16
cm
2
) is much greater than ground-state absorption cross-section value
(
σ
g
=
2.49 × 10
–22
cm
2
), suggesting that optical limiting phenomena are due to RSA.</description><subject>Absorption cross sections</subject><subject>Biochemistry</subject><subject>Biotechnology</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Constraining</subject><subject>Functional groups</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Materials Science</subject><subject>Medicinal Chemistry</subject><subject>Nonlinear optics</subject><subject>Optical properties</subject><subject>Original Paper</subject><subject>Single crystals</subject><issn>2585-7290</issn><issn>0366-6352</issn><issn>1336-9075</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9UctqHDEQFMYGL45_wCdBrplYjxlpJrew5GEw2IfkLLRSz66MVlIkzWFv-YeAP9BfYtkb8M2X7qKoqm4ohK4o-UwJkdeFUjGJjjDaESrJ0E0naEU5F91E5HCKVmwYh06yiZyjy1LchvS95GwUcoUe76M_7GNOO2ewjSHmp7__tDGQasy4LJtSXV0qWGx22psY4AsuNS-mLln7T7gkMPUVWQf-BbccHSwOMXgXQGccU3VGe5xyTJCrg4Ln-EZ7t3fVhS3WKfnGVBdD-YDOZu0LXP7fF-j392-_1j-727sfN-uvt51hktROcNEzA7OAyQqwEqaNFv3IJdHCGi7kPGvBgXEx0TbJCL1mch7owJiw1vIL9PGY2577s0Cp6iEuObSTig1Dz6Wg49hU7KgyOZaSYVYpu73OB0WJeqlAHStQrQL1WoGamokfTaWJwxbyW_Q7rmd4oo8c</recordid><startdate>20210901</startdate><enddate>20210901</enddate><creator>Raghavendra, S.</creator><creator>Kumar, C. S. Chidan</creator><creator>Kumar, D. J. Madhu</creator><creator>Al-Ghorbani, Mohammed</creator><creator>Alsalme, Ali</creator><creator>Quah, C. K.</creator><creator>Raghavendra, P. V.</creator><creator>Serrao, Felcy Jyothi</creator><creator>Dharmaprakash, S. M.</creator><general>Versita</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-9633-953X</orcidid></search><sort><creationdate>20210901</creationdate><title>Polymorphic donor–acceptor substituted chalcone: structural, spectral, dielectric and nonlinear optical properties for optical limiting applications</title><author>Raghavendra, S. ; Kumar, C. S. Chidan ; Kumar, D. J. Madhu ; Al-Ghorbani, Mohammed ; Alsalme, Ali ; Quah, C. K. ; Raghavendra, P. V. ; Serrao, Felcy Jyothi ; Dharmaprakash, S. 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Madhu</creatorcontrib><creatorcontrib>Al-Ghorbani, Mohammed</creatorcontrib><creatorcontrib>Alsalme, Ali</creatorcontrib><creatorcontrib>Quah, C. K.</creatorcontrib><creatorcontrib>Raghavendra, P. V.</creatorcontrib><creatorcontrib>Serrao, Felcy Jyothi</creatorcontrib><creatorcontrib>Dharmaprakash, S. M.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical papers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Raghavendra, S.</au><au>Kumar, C. S. Chidan</au><au>Kumar, D. J. Madhu</au><au>Al-Ghorbani, Mohammed</au><au>Alsalme, Ali</au><au>Quah, C. K.</au><au>Raghavendra, P. V.</au><au>Serrao, Felcy Jyothi</au><au>Dharmaprakash, S. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymorphic donor–acceptor substituted chalcone: structural, spectral, dielectric and nonlinear optical properties for optical limiting applications</atitle><jtitle>Chemical papers</jtitle><stitle>Chem. Pap</stitle><date>2021-09-01</date><risdate>2021</risdate><volume>75</volume><issue>9</issue><spage>4749</spage><epage>4758</epage><pages>4749-4758</pages><issn>2585-7290</issn><issn>0366-6352</issn><eissn>1336-9075</eissn><abstract>Herein, we report the third-order nonlinear absorption and optical limiting property of fluorinated polymorphic nonlinear optical (NLO) material 1-(3,4-dimethoxyphenyl)-3-(4-fluorophenyl) prop-2-en-1-one (abbreviated as PDPFO) based on reverse saturable absorption. The FTIR studies of optically transparent PDPFO single crystals confirm the presence of various functional groups. PDPFO is optically transparent in the visible wavelength region. The open aperture Z-scan technique showed the intensity-dependent nonlinear absorption
.
A decrease in normalized transmittance with input intensity indicated the optical limiting behavior at the wavelength 532 nm. The excited-state absorption cross-section value (
σ
ex
=
1.72 × 10
–16
cm
2
) is much greater than ground-state absorption cross-section value
(
σ
g
=
2.49 × 10
–22
cm
2
), suggesting that optical limiting phenomena are due to RSA.</abstract><cop>Warsaw</cop><pub>Versita</pub><doi>10.1007/s11696-021-01705-9</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-9633-953X</orcidid></addata></record> |
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subjects | Absorption cross sections Biochemistry Biotechnology Chemistry Chemistry and Materials Science Chemistry/Food Science Constraining Functional groups Industrial Chemistry/Chemical Engineering Materials Science Medicinal Chemistry Nonlinear optics Optical properties Original Paper Single crystals |
title | Polymorphic donor–acceptor substituted chalcone: structural, spectral, dielectric and nonlinear optical properties for optical limiting applications |
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