Polymorphic donor–acceptor substituted chalcone: structural, spectral, dielectric and nonlinear optical properties for optical limiting applications

Herein, we report the third-order nonlinear absorption and optical limiting property of fluorinated polymorphic nonlinear optical (NLO) material 1-(3,4-dimethoxyphenyl)-3-(4-fluorophenyl) prop-2-en-1-one (abbreviated as PDPFO) based on reverse saturable absorption. The FTIR studies of optically tran...

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Veröffentlicht in:Chemical papers 2021-09, Vol.75 (9), p.4749-4758
Hauptverfasser: Raghavendra, S., Kumar, C. S. Chidan, Kumar, D. J. Madhu, Al-Ghorbani, Mohammed, Alsalme, Ali, Quah, C. K., Raghavendra, P. V., Serrao, Felcy Jyothi, Dharmaprakash, S. M.
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container_end_page 4758
container_issue 9
container_start_page 4749
container_title Chemical papers
container_volume 75
creator Raghavendra, S.
Kumar, C. S. Chidan
Kumar, D. J. Madhu
Al-Ghorbani, Mohammed
Alsalme, Ali
Quah, C. K.
Raghavendra, P. V.
Serrao, Felcy Jyothi
Dharmaprakash, S. M.
description Herein, we report the third-order nonlinear absorption and optical limiting property of fluorinated polymorphic nonlinear optical (NLO) material 1-(3,4-dimethoxyphenyl)-3-(4-fluorophenyl) prop-2-en-1-one (abbreviated as PDPFO) based on reverse saturable absorption. The FTIR studies of optically transparent PDPFO single crystals confirm the presence of various functional groups. PDPFO is optically transparent in the visible wavelength region. The open aperture Z-scan technique showed the intensity-dependent nonlinear absorption . A decrease in normalized transmittance with input intensity indicated the optical limiting behavior at the wavelength 532 nm. The excited-state absorption cross-section value ( σ ex = 1.72 × 10 –16 cm 2 ) is much greater than ground-state absorption cross-section value ( σ g = 2.49 × 10 –22 cm 2 ), suggesting that optical limiting phenomena are due to RSA.
doi_str_mv 10.1007/s11696-021-01705-9
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subjects Absorption cross sections
Biochemistry
Biotechnology
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Constraining
Functional groups
Industrial Chemistry/Chemical Engineering
Materials Science
Medicinal Chemistry
Nonlinear optics
Optical properties
Original Paper
Single crystals
title Polymorphic donor–acceptor substituted chalcone: structural, spectral, dielectric and nonlinear optical properties for optical limiting applications
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