Fabrication and Luminescence Properties of La2O2S:Tb3+ Hollow Nanofibers

La 2 O 2 S:Tb 3+ hollow nanofibers were successfully fabricated by sulfurization of the relevant La 2 O 3 :Tb 3+ hollow nanofibers via double-crucible method. The morphology and properties of the products were investigated in detail by X-ray diffraction (XRD), scanning electron microscopy (SEM) and...

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Veröffentlicht in:Russian Journal of Physical Chemistry A 2021-07, Vol.95 (7), p.1418-1423
Hauptverfasser: Bi, Fei, Li, Jiaqi, Gai, Guangqing, Dong, Xiangting
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Sprache:eng
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Zusammenfassung:La 2 O 2 S:Tb 3+ hollow nanofibers were successfully fabricated by sulfurization of the relevant La 2 O 3 :Tb 3+ hollow nanofibers via double-crucible method. The morphology and properties of the products were investigated in detail by X-ray diffraction (XRD), scanning electron microscopy (SEM) and fluorescence spectrometry. La 2 O 2 S:Tb 3+ hollow nanofibers were pure hexagonal phase with space group P m 1 and were hollow-centered structure with the mean diameter of 160.03 ± 17.74 nm. Emission spectra indicate that La 2 O 2 S:Tb 3+ hollow nanofibers emit green light at 544 nm attributed to 5 D 4 → 7 F 5 energy levels transition of Tb 3+ ions. CIE analysis demonstrated that the light emitted by La 2 O 2 S:Tb 3+ hollow nanofibers corresponds to the green region, and color-tuned luminescence can be obtained by changing concentration of Tb 3+ ions. The obtained material could be applied in the field of optical telecommunication and optoelectronic devices. The possible formation mechanism of La 2 O 2 S:Tb 3+ hollow nanofibers was also proposed.
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024421070104