Fabrication and Luminescence Properties of La2O2S:Tb3+ Hollow Nanofibers
La 2 O 2 S:Tb 3+ hollow nanofibers were successfully fabricated by sulfurization of the relevant La 2 O 3 :Tb 3+ hollow nanofibers via double-crucible method. The morphology and properties of the products were investigated in detail by X-ray diffraction (XRD), scanning electron microscopy (SEM) and...
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Veröffentlicht in: | Russian Journal of Physical Chemistry A 2021-07, Vol.95 (7), p.1418-1423 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
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Zusammenfassung: | La
2
O
2
S:Tb
3+
hollow nanofibers were successfully fabricated by sulfurization of the relevant La
2
O
3
:Tb
3+
hollow nanofibers via double-crucible method. The morphology and properties of the products were investigated in detail by X-ray diffraction (XRD), scanning electron microscopy (SEM) and fluorescence spectrometry. La
2
O
2
S:Tb
3+
hollow nanofibers were pure hexagonal phase with space group
P
m
1 and were hollow-centered structure with the mean diameter of 160.03 ± 17.74 nm. Emission spectra indicate that La
2
O
2
S:Tb
3+
hollow nanofibers emit green light at 544 nm attributed to
5
D
4
→
7
F
5
energy levels transition of Tb
3+
ions. CIE analysis demonstrated that the light emitted by La
2
O
2
S:Tb
3+
hollow nanofibers corresponds to the green region, and color-tuned luminescence can be obtained by changing concentration of Tb
3+
ions. The obtained material could be applied in the field of optical telecommunication and optoelectronic devices. The possible formation mechanism of La
2
O
2
S:Tb
3+
hollow nanofibers was also proposed. |
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ISSN: | 0036-0244 1531-863X |
DOI: | 10.1134/S0036024421070104 |